(S)-(-)-isobutyl phenyl sulfoxide

Base Information

• Chemical Name: (S)-(-)-isobutyl phenyl sulfoxide
• CAS No.: 67501-04-6
• Molecular Formula: C₁₀H₁₄OS
• Molecular Weight: 182.287
• Mol file: 67501-04-6.mol

Synonyms:

Chemical Property of (S)-(-)-isobutyl phenyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-(-)-isobutyl phenyl sulfoxide

There total 14 articles about (S)-(-)-isobutyl phenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

(S)-(-)-(2-bromophenyl) isobutylsulfoxide → (S)-(-)-isobutyl phenyl sulfoxide (22456-89-9,67501-04-6,67529-48-0,72174-22-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

DOI:10.1021/jo502417j

Reference yield:

Isobutylthiobenzene (13307-61-4) → (R)-(+)-isobutyl phenyl sulfoxide (22456-89-9,67501-04-6,72174-22-2,67529-48-0) + (S)-(-)-isobutyl phenyl sulfoxide (22456-89-9,67501-04-6,67529-48-0,72174-22-2)

Guidance literature:

With peracetic acid; In water; at 0 ℃; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; educt as complex with β-cyclodextrin;

DOI:10.1021/jo00013a010

Reference yield:

Isobutylthiobenzene (13307-61-4) → (R)-(+)-isobutyl phenyl sulfoxide (22456-89-9,67501-04-6,72174-22-2,67529-48-0) + (S)-(-)-isobutyl phenyl sulfoxide (22456-89-9,67501-04-6,67529-48-0,72174-22-2)

Guidance literature:

With peracetic acid; In water; at 0 ℃; for 20h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; educt as complex with β-cyclodextrin;

DOI:10.1021/jo00013a010

upstream raw materials:

Isobutylthiobenzene

isobutyl phenyl sulfoxide

1,1'-sulfinylbisbenzene

di-iso-butylmagnesium