tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate

Base Information

Chemical Name:tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate
CAS No.:108008-88-4
Molecular Formula:C₃₂H₃₂FeN₃*F₆P
Molecular Weight:659.437
Hs Code.:

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Chemical Property of tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate

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Technology Process of tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate

There total 2 articles about tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: ammonium hexafluorophosphate

: heptacarbonyl(η5-cyclopentadienyl)ironmanganese(Fe-Mn)

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 108008-88-4
tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate

Guidance literature:: In tetrahydrofuran; CpFe(CO)2Mn(CO)5 reacted with 3 equiv of 2,6-Me2C6H3NC in THF in the dark under nitrogen atmosphere at room temp. for 4 min (IR monitoring of the reaction progress), NH4PF6 was added; mixt. was pumped to dryness, residue was washed with benzene, hexane, and recrystd. from CH2Cl2-ether-hexane; elem. anal.;

Reference yield: 49.2%

: 102-54-5,55404-68-7
ferrocene

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 558-32-7
tetramethylammonium hexafluorophosphate

: 108008-88-4
tris-2,6-dimethylphenyl isocyanide cyclopentadiene iron(II) hexafluorophosphate

Guidance literature:: With cerric ammonium nitrate; In ethanol; acetone; to stirring soln. of ferrocene cerric ammonium nitrate added, stirred for 10 min, isocyanide added, stirred overnight, solvent removed (vac.), product washed (hexane), dissolved in acetone, N(CH3)4PF6 added under stirring, stirred overnight; filtered (celite), solvent removed (vac.), residue washed (CH2Cl2), purified by chromy. (silica gel, acetone), recrystd. (ethanol); elem. anal.;
DOI:10.1016/j.ica.2011.01.025