[Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4]

Base Information

• Chemical Name: [Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4]
• CAS No.: 713497-19-9
• Molecular Formula: C₅₆H₅₆Pt₂S₂
• Molecular Weight: 1183.35
• Mol file: 713497-19-9.mol

Synonyms:

Chemical Property of [Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4]

There total 1 articles about [Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

cis-dichlorobis(diethylsulfide)platinum(II) (14873-92-8,20244-83-1,15337-84-5,15442-57-6) + water (7732-18-5) + biphenyl-2,2'-diyl-bis-lithium (16291-32-0) → (biphenyl((C2H5)2S)2 platinum)2 + [Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4] (714258-52-3,713497-19-9)

Guidance literature:

In diethyl ether; under N2; soln. of Li compd. in Et2O added dropwise to stirred suspn. ofPt complex in Et2O at -10°C; kept for 1 h; warmed to 0°C; kept for 1 h; hydrolyzed with H2O; org. phase sepd.; aq. phase extd. with CH2Cl2; CH2Cl2 extract combined with org. phase; left overnight over Na2SO4; evapd. to dryness; dissolvedin CH2Cl2; sepd. by column chromy. (silica gel, CH2Cl2-hexane); recryst d. (CH2Cl2-pentane); elem. anal.;

DOI:10.1021/ja030486u

Reference yield:

[Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4] (714258-52-3,713497-19-9) → {Pt(II)(Hbph)2(bpy)}

Guidance literature:

Multi-step reaction with 2 steps

1: dimethyl sulfoxide

2: toluene

In dimethyl sulfoxide; toluene;

DOI:10.1021/ja030486u

Reference yield:

[Pt2(μ-SEt2)2(η1-2,2'-biphenyl monoanion)4] (714258-52-3,713497-19-9) → [Pt(η1-2,2'-biphenyl monoanion)2(1,10-phenanthroline)] (713497-22-4)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethyl sulfoxide

2: dichloromethane

In dichloromethane; dimethyl sulfoxide;

DOI:10.1021/ja030486u

upstream raw materials:

cis-dichlorobis(diethylsulfide)platinum(II)

water

biphenyl-2,2'-diyl-bis-lithium

Downstream raw materials:

[Pt(η1-2,2'-biphenyl monoanion)2(1,10-phenanthroline)]