(P(CH₂CH₂CN)3)Cr(C(C₆H₅)C₄H₂NC(C₆H₅)C₄H₂N)2Cl

Base Information

• Chemical Name: (P(CH₂CH₂CN)3)Cr(C(C₆H₅)C₄H₂NC(C₆H₅)C₄H₂N)2Cl
• CAS No.: 80822-51-1
• Molecular Formula: C₅₃H₄₀ClCrN₇P
• Molecular Weight: 893.37
• Mol file: 80822-51-1.mol

Synonyms:

Chemical Property of (P(CH₂CH₂CN)3)Cr(C(C₆H₅)C₄H₂NC(C₆H₅)C₄H₂N)2Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (P(CH₂CH₂CN)3)Cr(C(C₆H₅)C₄H₂NC(C₆H₅)C₄H₂N)2Cl

There total 1 articles about (P(CH₂CH₂CN)3)Cr(C(C₆H₅)C₄H₂NC(C₆H₅)C₄H₂N)2Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(5,10,15,20-tetraphenylporphyrinato)chromium(III) (28110-70-5) + tris(2-cyanoethyl)phosphine (4023-53-4) → (P(CH2CH2CN)3)Cr(C(C6H5)C4H2NC(C6H5)C4H2N)2Cl (80822-51-1)

Guidance literature:

In toluene; Cr complex dissolving in dry toluene at 25°C in the presence of the ligand;

DOI:10.1021/ic00135a076

Reference yield:

(P(CH2CH2CN)3)Cr(C(C6H5)C4H2NC(C6H5)C4H2N)2Cl (80822-51-1) → Cr(TPP)(Cl)(PPh3)

Guidance literature:

With triphenylphosphine; In toluene; byproducts: P(CH2CH2CN)3; Cr complex dissolved in dry toluene reacting with PPh3 at 25°C; detd. spectrophotometrically; Kinetics;

DOI:10.1021/ic00135a076

Reference yield:

(P(CH2CH2CN)3)Cr(C(C6H5)C4H2NC(C6H5)C4H2N)2Cl (80822-51-1) → chloro(5,10,15,20-tetraphenylporphinato)chromium(III)(pyridine) (65013-13-0)

Guidance literature:

With pyridine; In toluene; byproducts: P(CH2CH2CN)3; Cr complex dissolved in dry toluene reacting with pyridine at 25°C; detd. spectrophotometrically; Kinetics;

DOI:10.1021/ic00135a076

upstream raw materials:

chloro(5,10,15,20-tetraphenylporphyrinato)chromium(III)

tris(2-cyanoethyl)phosphine

Downstream raw materials:

chloro(5,10,15,20-tetraphenylporphinato)chromium(III)(pyridine)

[Cr(5,10,15,20-tetraphenylporphinate)Cl(1-methylimidazole)]