[(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me₂C₆H₃))]ClO₄

Base Information

• Chemical Name: [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me₂C₆H₃))]ClO₄
• CAS No.: 244085-49-2
• Molecular Formula: C₂₅H₂₀N₃Pt*ClO₄
• Molecular Weight: 656.985
• Mol file: 244085-49-2.mol

Synonyms:

Chemical Property of [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me₂C₆H₃))]ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me₂C₆H₃))]ClO₄

There total 2 articles about [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me₂C₆H₃))]ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

platinum(II)Cl(6-phenyl-2,2'-bipyridine) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) + lithium perchlorate → [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me2C6H3))]ClO4 (244085-49-2)

Guidance literature:

In acetonitrile; stirring (10 min), pptn. on LiClO4 and Et2O addn.; drying, recrystn. (Et2O diffusion to MeCN soln.); elem. anal.;

DOI:10.1021/om990256h

Reference yield: 66.0%

ammonium hexafluorophosphate + platinum(II)Cl(6-phenyl-2,2'-bipyridine) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me2C6H3))]ClO4 (244085-49-2)

Guidance literature:

In methanol; acetonitrile; addn. of 2,6-dimethylphenyl isocyanide to suspn. of (C6H4(C5H3N)(C5H4N))PtCl in CH3CN, stirring for 10 min, pptn., addn. of methanol, filtration, evapn. of filtrate to dryness, dissolving in CH3OH, addn. of excess NH4PF6; pptn., filtration, recrystn. by vapor diffusion of diethyl ether into CH3CN, elem. anal.;

Reference yield: 69.0%

[(6-phenyl-2,2'-bipyridyl)Pt(CN(2,6-Me2C6H3))]ClO4 (244085-49-2) + lithium perchlorate + benzylamine (100-46-9) → [(6-phenyl-2,2'-bipyridyl)Pt(C(HN-2,6-Me2C6H3)(NHCH2Ph))]ClO4

Guidance literature:

In water; acetonitrile; refluxing (24 h), concg., pptn. on LiClO4 addn.; filtering, drying, recrystn. (Et2O diffusion to MeCN soln.); elem. anal.;

DOI:10.1021/om990256h

upstream raw materials:

2,6-dimethylphenyl isonitrile