1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate

Base Information

• Chemical Name: 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate
• CAS No.: 1638885-96-7
• Molecular Formula: C₁₇H₁₉N₂*F₆P
• Molecular Weight: 396.315
• Mol file: 1638885-96-7.mol

Synonyms:

Chemical Property of 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate

There total 2 articles about 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + N,N'-dimethylbenzimidazolium hexafluorophosphate (328312-77-2) → 1,3-dimethyl-2-phenethyl-1H-benzo[d]imidazolium hexafluorophosphate (1638885-92-3) + 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate (1638885-96-7)

Guidance literature:

With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; N-(2-(3-mesityl-2,3-dihydro-1H-imidazol-1-yl)ethyl)-2-methylpropan-2-amine; In toluene; at 100 ℃; for 16h; Overall yield = 69 %Spectr.; regioselective reaction;

DOI:10.1002/chem.201400303

Reference yield:

1,3-dimethylbenzimidazolium Iodide (7181-87-5) → 1,3-dimethyl-2-phenethyl-1H-benzo[d]imidazolium hexafluorophosphate (1638885-92-3) + 1,3-dimethyl-2-(1-phenylethyl)-1H-benzo[d]imidazolium hexafluorophosphate (1638885-96-7)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hexafluorophosphate / water; methanol / 20 °C

2: bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; N-(2-(3-mesityl-2,3-dihydro-1H-imidazol-1-yl)ethyl)-2-methylpropan-2-amine / toluene / 16 h / 130 °C

With potassium hexafluorophosphate; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; N-(2-(3-mesityl-2,3-dihydro-1H-imidazol-1-yl)ethyl)-2-methylpropan-2-amine; In methanol; water; toluene;

DOI:10.1002/chem.201400303

upstream raw materials:

1,3-dimethylbenzimidazolium Iodide

styrene

N,N'-dimethylbenzimidazolium hexafluorophosphate

Refernces