dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV)

Base Information

• Chemical Name: dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV)
• CAS No.: 1391351-31-7
• Molecular Formula: C₄₁H₄₉Cl₂N₃O₂Ti
• Molecular Weight: 734.645
• Mol file: 1391351-31-7.mol

Synonyms:

Chemical Property of dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV)

There total 1 articles about dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

dichlorobis(2,6-dimethylphenoxy)bis(tetrahydrofuran)titanium(IV) (104181-55-7,132152-04-6) + 1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene → dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV) (1391351-31-7)

Guidance literature:

In toluene; under N2, drybox or Schlenk technique; soln. of imine in toluene added to soln. of Ti-complex in toluene, mixt. stirred at room temp. for 4 h; evapn. under vac., residue washed with pentane, recrystn. from CH2Cl2/pentane; elem. anal.;

DOI:10.1016/j.jorganchem.2012.05.018

Reference yield:

dichloro(1-(1-(2,6-dimethylphenylimino)-2,2-dimethylpropyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)bis(2,6-dimethylphenoxy)titanium(IV) (1391351-31-7) → dichlorobis(2,6-dimethylphenoxy)bis(1-(2,4,6-trimethylphenyl)imidazole)titanium(IV) (1391351-32-8)

Guidance literature:

In tetrahydrofuran; pentane; under N2, drybox or Schlenk technique; diffusion of pentane into soln. of Ti-complex in THF at -35°C;

DOI:10.1016/j.jorganchem.2012.05.018

upstream raw materials:

dichlorobis(2,6-dimethylphenoxy)bis(tetrahydrofuran)titanium(IV)

Downstream raw materials:

dichlorobis(2,6-dimethylphenoxy)bis(1-(2,4,6-trimethylphenyl)imidazole)titanium(IV)