(C₆H₃(CH₂P(C₆H₁₁)2)2)NiCl

Base Information

• Chemical Name: (C₆H₃(CH₂P(C₆H₁₁)2)2)NiCl
• CAS No.: 1160697-77-7
• Molecular Formula: C₃₂H₅₁ClNiP₂
• Molecular Weight: 591.847
• Mol file: 1160697-77-7.mol

Synonyms:

Chemical Property of (C₆H₃(CH₂P(C₆H₁₁)2)2)NiCl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₆H₃(CH₂P(C₆H₁₁)2)2)NiCl

There total 1 articles about (C₆H₃(CH₂P(C₆H₁₁)2)2)NiCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

nickel(II) chloride hexahydrate + 1,3-bis(dicyclohexylphosphinomethyl)benzene (161868-97-9) → (C6H3(CH2P(C6H11)2)2)NiCl (1160697-77-7)

Guidance literature:

In ethanol; water; under Ar; soln. of Ni salt in degassed H2O added to EtOH soln. of ligand; heated to reflux; stirred under low reflux overnight; cooled; modifiedfrom C. J. Moulton, B. I. Shaw, J. Chem. Soc., Dalton Trans., 1976, 11, 1020; filtered; ppt. washed with cold EtOH; recrystd. from concd. soln. of pentane or hexane at -35°C; elem. anal.;

DOI:10.1021/ic8020194

Reference yield: 70.0%

(C6H3(CH2P(C6H11)2)2)NiCl (1160697-77-7) + lithium triethylborohydride (22560-16-3) → (C6H3(CH2P(C6H11)2)2)NiH (1160697-78-8)

Guidance literature:

In tetrahydrofuran; toluene; under Ar; Ni complex dissolved in toluene; cooled to 0°C (ice bath); soln. of LiEt3BH in THF added dropwise; warmed to room temp.; stirred overnight; volatiles removed under vac.; extd. in pentane; filtered; concd.; crystd. at -35°C; elem. anal.;

DOI:10.1021/ic8020194

Reference yield: 25.0%

(C6H3(CH2P(C6H11)2)2)NiCl (1160697-77-7) + potassium tri-sec-butyl-borohydride → (C6H3(CH2P(C6H11)2)2)NiH (1160697-78-8)

Guidance literature:

In tetrahydrofuran; under Ar;

DOI:10.1021/ic8020194

upstream raw materials:

1,3-bis(dicyclohexylphosphinomethyl)benzene

Downstream raw materials:

(C₆H₃(CH₂P(C₆H₁₁)2)2)NiH