CH₃Ir(CH₃O₂CCHCHCO₂CH₃)CO(P(C₆H₅)3)2

Base Information

• Chemical Name: CH₃Ir(CH₃O₂CCHCHCO₂CH₃)CO(P(C₆H₅)3)2
• CAS No.: 96164-74-8
• Molecular Formula: C₄₄H₄₁IrO₅P₂
• Molecular Weight: 903.974
• Mol file: 96164-74-8.mol

Synonyms:

Chemical Property of CH₃Ir(CH₃O₂CCHCHCO₂CH₃)CO(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of CH₃Ir(CH₃O₂CCHCHCO₂CH₃)CO(P(C₆H₅)3)2

There total 2 articles about CH₃Ir(CH₃O₂CCHCHCO₂CH₃)CO(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

trans-Ir(CO)(CH3)(PPh3)2 + dimethyl cis-but-2-ene-1,4-dioate (624-48-6) → CH3Ir(CH3O2CCHCHCO2CH3)CO(P(C6H5)3)2 (96164-74-8)

Guidance literature:

In benzene; mixt. of reagents in benzene was stirred for 5 min; hexane was added, filtered; elem. anal.;

DOI:10.1021/om00126a004

Reference yield:

trans-Ir(CO)(CH3)(PPh3)2 + dimethyl cis-but-2-ene-1,4-dioate (624-48-6) → CH3Ir(CO)(P(C6H5)3)2(CH3CO2CHCHCO2CH3) (96164-74-8)

Guidance literature:

In benzene; add. of maleate to suspn. of Ir-complex in benzene (inert atmosphere, glove box), stirring; left open in the inert atmosphere (glove box, several d), crystn., washed (small volume of benzene then 3/1 benzene/hexane); elem. anal.;

DOI:10.1016/0022-328X(86)82059-9

upstream raw materials:

dimethyl cis-but-2-ene-1,4-dioate