{η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium

Base Information

• Chemical Name: {η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium
• CAS No.: 128000-03-3
• Molecular Formula: C₁₅H₂₇Cl₂NSiTi
• Molecular Weight: 368.258
• Mol file: 128000-03-3.mol

Synonyms:

Chemical Property of {η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium

There total 1 articles about {η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + 2Li(1+)*C5H3(C(CH3)3)(Si(CH3)2NC(CH3)3)(2-)=Li2{C5H3(C(CH3)3)(Si(CH3)2NC(CH3)3)} (128000-01-1) → {η5:η1-3-(tert-butyl)-1-{(tert-butylamido)dimethylsilyl}cyclopentadienyl}dichlorotitanium (128000-03-3)

Guidance literature:

In tetrahydrofuran; under nitrogen or argon, soln. of Li2(C5H3(CMe3)(SiMe2NCMe3)) in THF treated with TiCl4(THF)2 at - 78 ° C, warming up to room temp. stirring for 2 h; evapn., extn. with pentane, filtration, cooling to -78 ° C afforded brown crystals, recrystn. from pentane at -78°C, elem. anal.;

upstream raw materials:

tetrachlorobis(tetrahydrofuran)titanium(IV)

2Li⁽¹⁺⁾*C₅H₃(C(CH₃)3)(Si(CH₃)2NC(CH₃)3)^(2-)=Li₂{C₅H₃(C(CH₃)3)(Si(CH₃)2NC(CH₃)3)}