[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

Base Information

Chemical Name:[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane
CAS No.:162460-33-5
Molecular Formula:C₃₈H₆₂OSi
Molecular Weight:562.995
Hs Code.:

[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

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Chemical Property of [(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

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Technology Process of [(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

There total 3 articles about [(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86561-83-3
(S,E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-en-1-ol

: 162460-33-5
[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) PDC, NaOAc / 1.) CH₂Cl₂; 2.) THF

2: 1.) (Me₂CHCH(Me))2BH, H₂O₂, NaOH; 2.) Dess-Martin reagent, NaHCO₃ / 1.) -10 deg C to rt., 16 h; 2.) CH₂Cl₂, 75 min

3: 1.) MgBr₂; 2.) t-BuLi / 1.) ether, -33 deg C, 10 min; 2.) t-BuLi, -78 deg C to -50 deg C then -33 deg C, 1 h

4: 1.) SOCl₂, pyridine / 1.) ether, 0 deg C; 2.) THF, -78 deg C to -30 deg C, 1.5 h

With pyridine; sodium hydroxide; dipyridinium dichromate; thionyl chloride; dihydrogen peroxide; tert.-butyl lithium; sodium acetate; bis-(1,2-dimethylpropyl)borane; sodium hydrogencarbonate; Dess-Martin periodane; magnesium bromide;
DOI:10.1016/0040-4039(94)88450-1

Reference yield:

: 162460-28-8
(1R,3aR,7aR)-1-((R)-1,5-dimethylhexyl)-3a,7a-dimethyloctahydroinden-4-one

: 162460-33-5
[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) H₂NNH₂; 2.) I₂, Et₃N / 1.) EtOH, reflux; 2.) THF, 0 deg C

2: 1.) MgBr₂; 2.) t-BuLi / 1.) ether, -33 deg C, 10 min; 2.) t-BuLi, -78 deg C to -50 deg C then -33 deg C, 1 h

3: 1.) SOCl₂, pyridine / 1.) ether, 0 deg C; 2.) THF, -78 deg C to -30 deg C, 1.5 h

With pyridine; thionyl chloride; iodine; tert.-butyl lithium; triethylamine; magnesium bromide; hydrazine;
DOI:10.1016/0040-4039(94)88450-1

Reference yield:

: 162460-32-4
(E)-(R)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-en-1-ol

: 162460-33-5
[(E)-(S)-1-[(1R,3aR,7aR)-1-((R)-1,5-Dimethyl-hexyl)-3a,7a-dimethyl-2,3,3a,6,7,7a-hexahydro-1H-inden-4-yl]-6-((S)-3,3-dimethyl-oxiranyl)-4-methyl-hex-3-enyl]-dimethyl-phenyl-silane

Guidance literature:: With pyridine; thionyl chloride; Yield given. Multistep reaction; 1.) ether, 0 deg C; 2.) THF, -78 deg C to -30 deg C, 1.5 h;
DOI:10.1016/0040-4039(94)88450-1