[PdCl₂(HP(C₆H₁₁)2)2]

Base Information

• Chemical Name: [PdCl₂(HP(C₆H₁₁)2)2]
• CAS No.: 155898-37-6
• Molecular Formula: C₂₄H₄₆Cl₂P₂Pd
• Molecular Weight: 573.903
• Mol file: 155898-37-6.mol

Synonyms:

Chemical Property of [PdCl₂(HP(C₆H₁₁)2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PdCl₂(HP(C₆H₁₁)2)2]

There total 1 articles about [PdCl₂(HP(C₆H₁₁)2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + dicyclohexylphosphane (829-84-5) → [PdCl2(HP(C6H11)2)2] (155898-37-6,64659-74-1)

Guidance literature:

In toluene; (N2); room temp.;

DOI:10.1039/a607334d

Reference yield: 64.0%

PdCl2(P(C6H11)2H)2 (64659-74-1,155898-37-6) → (Pd(P(C6H11)2)(Cl)(P(C6H11)2H))2

Guidance literature:

With PhONa; In toluene; byproducts: NaCl, C6H5OH; PhONa is added to a suspension of (PdCl2(PCy2H)2) in toluene under nitrogen, stirred 3 h at ambient temp.; solvent is evapd., residue is extd. (CHCl3), concd., pptd. (acetone), filtn., drying (vac.); elem. anal.;

Reference yield: 46.0%

PdCl2(P(C6H11)2H)2 (64659-74-1,155898-37-6) + sodium phenoxide (139-02-6) → C60H98O2P4Pd2

Guidance literature:

In toluene; byproducts: NaCl, H2, C6H5OH; suspension of (PdCl2(PCy2H)2) and PhONa in toluene is stirred 3 h at 50°C under nitrogen, suspension is left overnight at ambient temp.; filtn., concn., acetone is added, pptn., filtn., drying (vac.); elem. nal.;

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

dicyclohexylphosphane

Downstream raw materials:

bis(μ-dicyclohexylphosphido)bis[(dicyclohexylphosphine)palladium(I)]

chloro(μ-dicyclohexylphosphido)tris(dicyclohexylphosphine)dipalladium(I)