{Rh(CO)2(P(C₆H₅)3)3}⁽¹⁺⁾*ClO₄^(1-)={Rh(CO)2(P(C₆H₅)3)3}ClO₄

Base Information

• Chemical Name: {Rh(CO)2(P(C₆H₅)3)3}⁽¹⁺⁾*ClO₄^(1-)={Rh(CO)2(P(C₆H₅)3)3}ClO₄
• CAS No.: 25300-54-3
• Molecular Formula: C₅₆H₄₅O₂P₃Rh*ClO₄
• Molecular Weight: 1045.25

Synonyms:

Chemical Property of {Rh(CO)2(P(C₆H₅)3)3}⁽¹⁺⁾*ClO₄^(1-)={Rh(CO)2(P(C₆H₅)3)3}ClO₄

Chemical Property:

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Safty Information:

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MSDS Files:

Useful:

Technology Process of {Rh(CO)2(P(C₆H₅)3)3}⁽¹⁺⁾*ClO₄^(1-)={Rh(CO)2(P(C₆H₅)3)3}ClO₄

There total 1 articles about {Rh(CO)2(P(C₆H₅)3)3}⁽¹⁺⁾*ClO₄^(1-)={Rh(CO)2(P(C₆H₅)3)3}ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Rh(3+)*3ClO4(1-)*99H2O=Rh(ClO4)3*99H2O → {Rh(CO)2(P(C6H5)3)3}(1+)*ClO4(1-)={Rh(CO)2(P(C6H5)3)3}ClO4 (25300-54-3,52612-79-0)

Guidance literature:

With triphenyl phosphine; carbon monoxide; In ethanol; freshly prepared hydrated Rh-perchlorate dissolved in abs. alcohol, CO gas passed throuh soln. under reflux for 15 min., PPh3 added to refluxing soln., CO gas bubbled for another 1 h; soln. cooled, solvent removed under reduced pressure, crystn. on trituration with abs. alcohol, washed with abs. alcohol and benzene, stored over CaCl2 in a desiccator for drying;

Reference yield: 90.0%

{Rh(CO)2(P(C6H5)3)3}(1+)*ClO4(1-)={Rh(CO)2(P(C6H5)3)3}ClO4 (25300-54-3,52612-79-0) + potassium hydroxide → carbonyl(hydroxy)bis(triphenylphosphine)rhodium(I) (32354-36-2,24444-24-4)

Guidance literature:

In methanol; acetone; byproducts: CO, P(C6H5)3, KClO4; addn. of a soln. of KOH in methanol to an equimolar soln. of the Rh-compd. in acetone; sepn. of KClO4 after 10 min. by filtration, removing the solvent in a vacuum, treating with benzene, filtration, evapn., addn. of hexane, filtration, washing with hexane, drying in air, elem. anal.;

Reference yield: 80.0%

{Rh(CO)2(P(C6H5)3)3}(1+)*ClO4(1-)={Rh(CO)2(P(C6H5)3)3}ClO4 (25300-54-3,52612-79-0) + sodium tetraphenyl borate (143-66-8) → {Rh(CO)(P(C6H5)3)2(S2CP(C6H5)3)}(1+)*B(C6H5)4(1-) = {Rh(CO)(P(C6H5)3)2(S2CP(C6H5)3)}B(C6H5)4

Guidance literature:

With carbon disulfide; triphenylphosphine; In methanol; rhodium complex mixed with PPh3 (methanol); CS2 added; NaBPh4 added (methanol); cooled below 0°C for 30 min;; ppt. filtered; washed (cold methanol); dried in air; elem. anal.;;

Downstream raw materials:

carbonyl(hydroxy)bis(triphenylphosphine)rhodium(I)

[Rh(CO)(C₁₂H₆N₂(CH₃)2)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₂H₆N₂(CH₃)2)(P(C₆H₅)3)2]ClO₄

[Rh(CO)(C₁₈H₁₂N₂)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₈H₁₂N₂)(P(C₆H₅)3)2]ClO₄

[Rh(CO)(C₁₂H₆N₂(C₆H₅)2)(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CO)(C₁₂H₆N₂(C₆H₅)2)(P(C₆H₅)3)2]ClO₄

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