(2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane

Base Information

• Chemical Name: (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane
• CAS No.: 330583-51-2
• Molecular Formula: C₃₉H₄₈GeS₄
• Molecular Weight: 717.664
• Mol file: 330583-51-2.mol

Synonyms:

Chemical Property of (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane

There total 6 articles about (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

sulfur (10544-50-0) + (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)GeH2 (330583-46-5) → (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane (330583-51-2) + (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5,6,7-hexathiagermepane (330583-50-1)

Guidance literature:

In neat (no solvent); in Schlenk tube mixed dihydrogermane and 30-40 equiv. of S8 and heated to 160-170°C for 15-20 min; excess of S removed by recrystn., chromy; elem. anal.;

DOI:10.1246/cl.2001.60

Reference yield:

(2,6-dimesitylphenyl)lithium → (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane (330583-51-2)

Guidance literature:

Multi-step reaction with 3 steps

3: neat (no solvent)

In neat (no solvent);

DOI:10.1246/cl.2001.60

Reference yield:

(2,4,6-triisopropylphenyl)magnesium bromide (108894-99-1) → (2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5-tetrathiagermolane (330583-51-2)

Guidance literature:

Multi-step reaction with 3 steps

3: neat (no solvent)

In neat (no solvent);

DOI:10.1246/cl.2001.60

upstream raw materials:

sulfur

(2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)GeH₂

(2,4,6-triisopropylphenyl)(2,6-dimesitylphenyl)-1,2,3,4,5,6,7-hexathiagermepane

(2,4,6-triisopropylphenyl)magnesium bromide

Downstream raw materials:

(2,6-dimesitylphenyl)(2,4,6-triisopropylphenyl)Ge(SH)2