(S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

Base Information

Chemical Name:(S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene
CAS No.:1423035-64-6
Molecular Formula:C₁₂H₁₅Br
Molecular Weight:239.155
Hs Code.:

Synonyms:

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Chemical Property of (S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

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Technology Process of (S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

There total 4 articles about (S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: C₁₃H₁₈BrO₄P

: 557-20-0
diethylzinc

: 1423035-64-6
(S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

Guidance literature:: diethylzinc; With n-butyllithium; C₂₁H₃₅N₂O⁽¹⁺⁾*F₆P^(1-); copper(II) bis(trifluoromethanesulfonate); In hexane; ethyl acetate; at 25 ℃; Schlenk technique; Inert atmosphere;

C₁₃H₁₈BrO₄P; In hexane; ethyl acetate; at 25 ℃; for 120h; enantioselective reaction; Catalytic behavior; Schlenk technique; Inert atmosphere;
DOI:10.1002/chem.201203969

Reference yield:

: C₁₄H₂₀BrO₄P

: 557-20-0
diethylzinc

: 1423035-64-6
(S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

: (R)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

Guidance literature:: With n-butyllithium; copper(I) trifluoromethanesulfonate benzene complex; (S)-1-(2,6-diisopropylphenyl)-3-(1-hydroxy-4-methylpentan-2-yl)imidazolium hexafluorophosphate; In hexane; ethyl acetate; at 0 - 20 ℃; for 72h; Overall yield = 68 %; Overall yield = 81 mg; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.joc.6b02888

Reference yield:

: 1374647-39-8
(E)-1’-bromo-2’-(4-bromobut-2-en-2-yl)benzene

: 925-90-6
ethylmagnesium bromide

: 1423035-64-6
(S)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

: (R)-1′-bromo-2′-(3-methylpent-1-en-3-yl)benzene

: C₁₂H₁₅Br

Guidance literature:: (E)-1’-bromo-2’-(4-bromobut-2-en-2-yl)benzene; With copper(I) thiophene-2-carboxylate; C₃₅H₃₉O₇P; In dichloromethane; at 20 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

ethylmagnesium bromide; In diethyl ether; dichloromethane; at -78 ℃; for 1h; Overall yield = 54 %; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.organomet.9b00194