toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)

Base Information

Chemical Name:toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)
CAS No.:86475-86-7
Molecular Formula:C₂₇H₂₆O₉
Molecular Weight:494.498
Hs Code.:

toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzo<d>naphtho<1,2-b>pyran)

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)

Chemical Property:

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MSDS Files:: SDS file from LookChem

Useful:

Technology Process of toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)

There total 1 articles about toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77879-90-4,78037-26-0
gilvocarcin V

: 86475-86-7
4-β-fucofuranosyl-1-hydroxy-10,12-dimethoxy-8-vinyl-6H-benzo-naphtho<1,2-b> pyran-6-one

: 77879-90-4,78037-26-0
4-α-fucofuranosyl-1-hydroxy-10,12-dimethoxy-8-vinyl-6H-benzo-naphtho<1,2-b> pyran-6-one

Guidance literature:: With toluene-4-sulfonic acid; In acetonitrile; for 10h; Product distribution; Heating; other reagent and solvent;
DOI:10.1016/S0040-4020(01)91834-4

Reference yield:

: 86475-86-7
toromycin (1-hydroxy-4(3,4,5-trihydroxy-6-methyl-2H-tetrahydropyran-2-yl)-10,12-dimethoxy-6-oxo-8-vinyl-6H-benzonaphtho<1,2-b>pyran)

: hexahydrotoromycin

Guidance literature:: Multi-step reaction with 2 steps

1: NaBH₄ / methanol; dioxane / Ambient temperature

2: 260 mg / H₂ / PtO₂ / methanol / 1 h / Ambient temperature

With sodium tetrahydroborate; hydrogen; platinum(IV) oxide; In 1,4-dioxane; methanol;
DOI:10.1248/cpb.28.3601