(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

Base Information

Chemical Name:(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester
CAS No.:192313-65-8
Molecular Formula:C₅₅H₅₈O₉
Molecular Weight:863.06
Hs Code.:

(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

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Chemical Property of (S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

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Technology Process of (S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

There total 6 articles about (S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1072-86-2,1460-57-7,1792-81-0,54383-22-1,57794-08-8,931-17-9
(1R,2R)-trans-1,2-cyclohexanediol

: 192313-65-8
(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Br₂; 2.) Et₄NBr, 4 Angstroem molecular sieves / 1.) CH₂Cl₂; 2.) CH₂Cl₂/DMF, 18 h, RT

2: 39 percent / p-TsOH / benzene / 20 h / Heating

3: 1.) TMSCl, NaI, NEt₃ / 1.) MeCN, 3 h, RT; 2.) 1 h, RT

4: 91 percent / 30percent H₂O₂, pyridine / CH₂Cl₂ / 1 h / 0 °C

5: 1.) (Bu₃Sn)2O, 2.) CsF / 1.) toluene, reflux, 3 h; 2.) DME, 3 h, RT

With pyridine; chloro-trimethyl-silane; 4 A molecular sieve; tetraethylammonium bromide; dihydrogen peroxide; bromine; toluene-4-sulfonic acid; triethylamine; cesium fluoride; bis(tri-n-butyltin)oxide; sodium iodide; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(97)00832-0

Reference yield:

: 169532-17-6,116391-11-8
ethyl 2,3,4-tri-O-benzyl-1-thio-α/β-L-fucopyranoside

: 192313-65-8
(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) Br₂; 2.) Et₄NBr, 4 Angstroem molecular sieves / 1.) CH₂Cl₂; 2.) CH₂Cl₂/DMF, 18 h, RT

2: 39 percent / p-TsOH / benzene / 20 h / Heating

3: 1.) TMSCl, NaI, NEt₃ / 1.) MeCN, 3 h, RT; 2.) 1 h, RT

4: 91 percent / 30percent H₂O₂, pyridine / CH₂Cl₂ / 1 h / 0 °C

5: 1.) (Bu₃Sn)2O, 2.) CsF / 1.) toluene, reflux, 3 h; 2.) DME, 3 h, RT

With pyridine; chloro-trimethyl-silane; 4 A molecular sieve; tetraethylammonium bromide; dihydrogen peroxide; bromine; toluene-4-sulfonic acid; triethylamine; cesium fluoride; bis(tri-n-butyltin)oxide; sodium iodide; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(97)00832-0

Reference yield:

: 162222-93-7
(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-Tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexanol

: 192313-65-8
(S)-3-Phenyl-2-{3-[(1R,2R)-2-((2S,3S,4R,5R,6S)-3,4,5-tris-benzyloxy-6-methyl-tetrahydro-pyran-2-yloxy)-cyclohexyloxy]-phenoxy}-propionic acid benzyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 39 percent / p-TsOH / benzene / 20 h / Heating

2: 1.) TMSCl, NaI, NEt₃ / 1.) MeCN, 3 h, RT; 2.) 1 h, RT

3: 91 percent / 30percent H₂O₂, pyridine / CH₂Cl₂ / 1 h / 0 °C

4: 1.) (Bu₃Sn)2O, 2.) CsF / 1.) toluene, reflux, 3 h; 2.) DME, 3 h, RT

With pyridine; chloro-trimethyl-silane; dihydrogen peroxide; toluene-4-sulfonic acid; triethylamine; cesium fluoride; bis(tri-n-butyltin)oxide; sodium iodide; In dichloromethane; benzene;
DOI:10.1016/S0040-4039(97)00832-0