Pt(CH₃)2(CH₂(P(C₆H₅)2)2)

Base Information

• Chemical Name: Pt(CH₃)2(CH₂(P(C₆H₅)2)2)
• CAS No.: 52595-90-1
• Molecular Formula: C₂₇H₂₈P₂Pt
• Molecular Weight: 609.547
• Mol file: 52595-90-1.mol

Synonyms:

Chemical Property of Pt(CH₃)2(CH₂(P(C₆H₅)2)2)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Pt(CH₃)2(CH₂(P(C₆H₅)2)2)

There total 2 articles about Pt(CH₃)2(CH₂(P(C₆H₅)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Pt2(CH3)4(CH2(P(C6H5)2)2)2 (79870-63-6) → Pt(CH3)2(CH2(P(C6H5)2)2) (52595-90-1)

Guidance literature:

With catalyst: S(CH₃)2 or CH₂(P(C₆H₅)2)2; In benzene-d6; (sealed tube, 48 h, 60 °C); quant. conversion; react. mechanism discussed; not isolated.; 1H NMR spectrum of react. soln.; Kinetics;

Reference yield:

Pt2(CH3)3(P(C6H5)2CH2P(C6H5)2)2(1+)*PF6(1-)=Pt2(CH3)3(P(C6H5)2CH2P(C6H5)2)2PF6 → Pt(CH3)2(CH2(P(C6H5)2)2) (52595-90-1) + Pt(CH3)(NC5H5)(P(C6H5)2CH2P(C6H5)2)(1+)*NO3(1-)=Pt(CH3)NC5H5(P(C6H5)2CH2P(C6H5)2)NO3

Guidance literature:

In perdeuteriopyridine; Irradiation (UV/VIS); Pt-complex was photolysed in C5D5N;

DOI:10.1139/v84-347

Reference yield: 87.0%

Ag4I4(PPh3)4 (cube isomer) (54937-07-4) + Pt(CH3)2(CH2(P(C6H5)2)2) (52595-90-1) + bis-diphenylphosphinomethane (2071-20-7) → (CH3)2Pt(CH2(P(C6H5)2)2)2AgI (100468-98-2)

Guidance literature:

In dichloromethane; a mixt. of Pt-compd. (0.164 mmol) and dppm (0.182 mmol) in CH2Cl2 was left to stand for 15 min at -30°C; a soln. of Ag-compd. (0.041 mmol) in CH2Cl2 was added to the cooled react. mixt. which was shaken and put aside at -60°C for 30 min;; the solvent was removed under reduced pressure and the oily residue triturated with diethyl ether and then with MeOH; elem. anal.;;

DOI:10.1039/DT9850001677

upstream raw materials:

Pt₂(CH₃)4(CH₂(P(C₆H₅)2)2)2

Downstream raw materials:

Pt(CH₂(P(C₆H₅)2)2)2(CH₃)2

(CH₃)2Pt(CH₂(P(C₆H₅)2)2)2Pd(CH₃)⁽¹⁺⁾

(CH₃)2Pt(CH₂(P(C₆H₅)2)2)2AgI