Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester

Base Information

• Chemical Name: Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester
• CAS No.: 741708-81-6
• Molecular Formula: C₁₈H₁₈Cl₆O₉S
• Molecular Weight: 623.12
• Mol file: 741708-81-6.mol

Synonyms:

Chemical Property of Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester

There total 1 articles about Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Carbonic acid (1R,3S,4R,4aR,9aR)-6,6,8,8-tetraisopropyl-3-phenylsulfanyl-1-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-2,5,7,9-tetraoxa-6,8-disila-benzocyclohepten-4-yl ester 2,2,2-trichloro-ethyl ester → Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester (741708-81-6)

Guidance literature:

With tetrabutyl ammonium fluoride; acetic acid; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/j.tetlet.2004.05.126

Reference yield:

t-butyldimethylsiyl triflate (69739-34-0) + Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester (741708-81-6) → Carbonic acid (2S,3R,4R,5R,6R)-4,5-bis-(tert-butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester

Guidance literature:

With 2,6-dimethylpyridine; In N,N-dimethyl-formamide; at 60 - 100 ℃;

DOI:10.1016/j.tetlet.2004.05.126

Reference yield:

tert-butyldiphenylsilyl triflate (92886-86-7) + Carbonic acid (2S,3R,4S,5S,6R)-4,5-dihydroxy-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester (741708-81-6) → Carbonic acid (2S,3R,4R,5R,6R)-4,5-bis-(tert-butyl-diphenyl-silanyloxy)-2-phenylsulfanyl-6-(2,2,2-trichloro-ethoxycarbonyloxymethyl)-tetrahydro-pyran-3-yl ester 2,2,2-trichloro-ethyl ester

Guidance literature:

With 2,6-dimethylpyridine; In N,N-dimethyl-formamide; at 60 - 100 ℃;

DOI:10.1016/j.tetlet.2004.05.126