carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium

Base Information

• Chemical Name: carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium
• CAS No.: 103623-61-6
• Molecular Formula: C₄₄H₃₈ClNOP₂Ru
• Molecular Weight: 795.262
• Mol file: 103623-61-6.mol

Synonyms:

Chemical Property of carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium

There total 1 articles about carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4-vinylpyridine (100-43-6,329041-72-7) + (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) → carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium (103623-61-6,108031-50-1,108031-71-6)

Guidance literature:

In tetrahydrofuran; addn. of 4-vinyl pyridine to Ru complex suspension under N2; stirring, 25°C, 24h; pptn.; filtration in air (sintered glass disc); washing (hexane); keeping in vac., 2h; elem. anal.;

DOI:10.1016/S0277-5387(00)87115-6

Reference yield: 85.0%

2-vinylpyridine (100-69-6,25014-15-7,27476-03-5,329041-71-6) + carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium (103623-61-6,108031-50-1,108031-71-6) → RuCl(CH2CH2(C5H4N))(CO)(P(C6H5)3)2

Guidance literature:

In tetrahydrofuran; addn. of 2-vinylpyridine to Ru complex suspension; stirring, 14h; evapn.; washing (hexane); crystn. (benzene/hexane); elem. anal.;

DOI:10.1016/S0277-5387(00)87115-6

Reference yield: 82.0%

carbonylchlorohydrido bis(triphenylphosphine)4-vinyl pyridine ruthenium (103623-61-6,108031-50-1,108031-71-6) + acrylonitrile (107-13-1,25014-41-9) → carbonylchloro(1-cyanoethyl) bis(triphenylphosphine)4-vinyl pyridineruthenium

Guidance literature:

In tetrahydrofuran; byproducts: 4-vinylpyridine; addn. of acrylonitrile to Ru complex suspension; stirring, 25°C, 24h; evapn.; washing (hexane); crystn. (benzene/hexane); elem. anal.;

DOI:10.1016/S0277-5387(00)87115-6

upstream raw materials:

4-vinylpyridine

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

Downstream raw materials:

{RuH(OC₆H₃(OCH₃)CHO)(CO)(P(C₆H₅)3)2}

carbonylhydrido(salicylaldehydato)bis(triphenylphosphine) ruthenium

carbonylchlorodithioformato-bis(triphenylphosphine)ruthenium

(8-quinolinolato)(hydrido)(carbonyl)bis(triphenylphosphine)ruthenium(II)