(R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III)

Base Information

• Chemical Name: (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III)
• CAS No.: 697807-13-9
• Molecular Formula: C₇₄H₆₅N₂O₂Si₂Y
• Molecular Weight: 1159.42
• Mol file: 697807-13-9.mol

Synonyms:

Chemical Property of (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III)

There total 2 articles about (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(R)-3,3'-(triphenylsilyl)-1,1'-bi-2,2'naphthol (126911-86-2,111795-33-6,111822-69-6) + [Y(o-C6H4CH2NMe2)3] → (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III) (697807-13-9,883107-16-2)

Guidance literature:

In toluene; reaction of yttrium compd. with binaphthole deriv. in toluene at 25°C for 12 h;

DOI:10.1021/ja058287t

Reference yield:

(R)-3,3'-(triphenylsilyl)-1,1'-bi-2,2'naphthol (126911-86-2,111795-33-6,111822-69-6) + [Y(o-C6H4CH2NMe2)3] → (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III) (697807-13-9,883107-16-2)

Guidance literature:

In toluene; 1:1 mixt. at 25°C for 12 h;

DOI:10.1039/b316096c

Reference yield:

propylamine (107-10-8,42939-71-9) + (R)-(3,3'-bis(triphenylsilyl)-2,2'-oxido-1,1'-binaphthyl)(2-(dimethylaminomethyl)phenyl)(dimethylaminomethylphenyl)yttrium(III) (697807-13-9,883107-16-2) → (R)-(C10H5(SiPh3))2O2Y(n-propylamide)(n-propylamine)

Guidance literature:

reaction of yttrium compd. with 2 equiv. of amine;

DOI:10.1021/ja058287t

upstream raw materials:

(R)-3,3'-(triphenylsilyl)-1,1'-bi-2,2'naphthol