[Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2]

Base Information

• Chemical Name: [Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2]
• CAS No.: 852993-25-0
• Molecular Formula: C₂₄H₂₈Cl₂N₂O₂Pd₂
• Molecular Weight: 660.245
• Mol file: 852993-25-0.mol

Synonyms:

Chemical Property of [Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2]

There total 1 articles about [Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

[Pd(acetonyl)Cl] + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2] (852993-25-0)

Guidance literature:

In acetonitrile; Me2C6H3NC (1 equiv.) added to cooled soln. (0°C) of Pd complex inMeCN; stirred at 0°C for 5 min; concd.; Et2O added; stirred at 0°C for 10 min; suspn. filtered off; washed with Et2O; air dried; elem. anal.;

DOI:10.1021/om048999c

Reference yield: 71.0%

[Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2] (852993-25-0) → [Pd2(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)2(μ-Cl)2] (852993-27-2)

Guidance literature:

In chloroform; soln. of Pd complex in CHCl3 stirred at 45°C for 1 h; filtered through Celite; filtrate concd.; Et2O added; filtered; filtrateconcd. to dryness; stirred with n-pentane at -10°C for 1 h; filt ered; solid air dried; elem. anal.;

DOI:10.1021/om048999c

Reference yield:

[Pd2(CH2C(O)Me)2(μ-Cl)2(2,6-xylyl isocyanide)2] (852993-25-0) → [Pd(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)Cl(NCMe)] (852993-29-4)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: chloroform

In chloroform; toluene;

DOI:10.1021/om048999c

upstream raw materials:

2,6-dimethylphenyl isonitrile

Downstream raw materials:

[Pd2(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)2(μ-Cl)2]

[Pd(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)Cl(NCMe)]

[Pd(κ2-C,O-C(NHC6H3-2,6-Me2)CHC(O)Me)Cl(PPh3)]