pentaphenylruthenocene

Base Information

• Chemical Name: pentaphenylruthenocene
• CAS No.: 98772-73-7
• Molecular Formula: C₄₀H₃₀Ru
• Molecular Weight: 611.748
• Mol file: 98772-73-7.mol

Synonyms:

Chemical Property of pentaphenylruthenocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of pentaphenylruthenocene

There total 2 articles about pentaphenylruthenocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

bromodicarbonyl(η-pentaphenylcyclopentadienyl)ruthenium + sodium cyclopentadienide → pentaphenylruthenocene (98772-73-7) + [(η(5)-pentaphenylcyclopentadienyl)Ru(μ-CO)(CO)]2

Guidance literature:

In tetrahydrofuran; N2-atmosphere; stirring Ru-complex with excess of NaCp (room temp., 18 h); in air; filtration, solvent removal (vac.), drying (vac., 200°C, 5 h), treatment with CH2Cl2, chromy. (CH2Cl2/hexane=3:7), evapn., recrystn. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/S0022-328X(98)00622-6

Reference yield: 12.0%

(cyclooctadienyl)(cyclopentadienyl)ruthenium chloride + 1,2,3,4,5-pentaphenylcyclopentadiene (2519-10-0) → pentaphenylruthenocene (98772-73-7)

Guidance literature:

With BuLi; In tetrahydrofuran; N2-atmosphere; stirring Ru-complex with slight excess of LiC5Ph5 (prepd.from equimolar amts. of HC5Ph5 and BuLi) for 18 h; in air; solvent removal, chromy. (CH2Cl2/hexane=3:7), evapn., fractionalcrystn. (CH2Cl2/hexane);

DOI:10.1016/S0022-328X(98)00622-6

upstream raw materials:

1,2,3,4,5-pentaphenylcyclopentadiene