(para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine

Base Information

• Chemical Name: (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine
• CAS No.: 247234-61-3
• Molecular Formula: C₃₂H₃₀CoO₃P
• Molecular Weight: 552.555
• Mol file: 247234-61-3.mol

Synonyms:

Chemical Property of (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine

There total 1 articles about (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

dicobalt octacarbonyl + 4-tert-butylbenzyl chloride (19692-45-6) + triphenylphosphine (603-35-0) → (para-(t)butylbenzyl)cobalt tricarbonyl triphenylphosphine (247234-61-3)

Guidance literature:

With Na-amalgam; In diethyl ether; byproducts: NaCl; inert atmosphere; treatment of Co2(CO)8 with Na/Hg, filtration, addn. of aryl chloride (-20°C), stirring (-20°C, 4 h; then room temp., 1 h), filtration, PPh3 addn., stirring for 9 h; evapn., repeated recrystn. (layering Et2O soln. with hexane); elem. anal.; further intermediates: Na(Co(CO)4), 4-t-BuC6H4CH2C(O)Co(CO)3(PPh3);

DOI:10.1016/S0022-328X(99)00157-6

upstream raw materials:

4-tert-butylbenzyl chloride

triphenylphosphine