Fe₂(CO)6(C₆H₁₁CHCH₃NCHCO₂CH₃)

Base Information

• Chemical Name: Fe₂(CO)6(C₆H₁₁CHCH₃NCHCO₂CH₃)
• CAS No.: 290304-73-3
• Molecular Formula: C₁₇H₁₉Fe₂NO₈
• Molecular Weight: 477.034
• Mol file: 290304-73-3.mol

Synonyms:

Chemical Property of Fe₂(CO)6(C₆H₁₁CHCH₃NCHCO₂CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Fe₂(CO)6(C₆H₁₁CHCH₃NCHCO₂CH₃)

There total 2 articles about Fe₂(CO)6(C₆H₁₁CHCH₃NCHCO₂CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

diiron nonacarbonyl (15321-51-4) + C6H11CHCH3NCHCO2CH3 → Fe2(CO)6(C6H11CHCH3NCHCO2CH3) (290304-73-3,290323-55-6)

Guidance literature:

In tetrahydrofuran; byproducts: Fe3(CO)12; imino ester added under N2 to a stirred susp. of Fe carbonyl in THF in a molar ratio of 1:2; soln. turned dark-purple; stirred for 16 h; the color of soln. changed to red-brown; evapd., dissolved in min. CH2Cl2 and sepd. on the column with SiO2; isolated by column chromy. on SiO2 (eluent pentane/Et2O); purified by recrystallization from pentane at -60°; identified by IR, NMR and mass spectra; obtained as a mixt. of two diastereomeres in 3:1 ratio;

DOI:10.1021/om9910266

Reference yield: 10.0%

diiron nonacarbonyl (15321-51-4) + C6H11CHCH3NCHCO2CH3 → Fe2(CO)6(C3H7NCHCO2CH2CH3)2 + Fe2(CO)6(C6H11CHCH3NCHCO2CH3) (290304-73-3,290323-55-6)

Guidance literature:

In toluene; byproducts: Fe3(CO)12; imino ester added under N2 to a stirred susp. of Fe carbonyl in toluenein a molar ratio of 1:2; soln. turned dark-purple; stirred for 16 h; the color of soln. changed to red-brown; evapd., dissolved in min. CH2Cl2 and sepd. on the column with SiO2; isolated by column chromy. on SiO2 (eluent pentane/Et2O); purified by recrystallization from pentane at -60°; identified by IR, NMR and mass spectra; obtained as a mixt. of two diastereomeres in 3:1 ratio;

DOI:10.1021/om9910266

upstream raw materials:

diiron nonacarbonyl