Technology Process of trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)
There total 6 articles about trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium carbonate;
In
methanol; dichloromethane;
for 4h;
Reflux;
DOI:10.1039/c1dt00004g
- Guidance literature:
-
With
K2CO3;
In
methanol; dichloromethane;
to soln. of tin complex in CH2Cl2-MeOH (4:1), K2CO3 was added, refluxed for 4 h; washed with water, dried over MgSO4, evapd. in vac., filtered through alumina column (CHCl3-MeOH, 99:1);
DOI:10.1039/c1dt00004g
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / tetrahydrofuran / 48 h / 20 °C
2: tin(II) chloride dihdyrate / pyridine / Reflux
3: potassium carbonate / methanol; dichloromethane / 4 h / Reflux
With
tin(II) chloride dihdyrate; potassium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
tetrahydrofuran; pyridine; methanol; dichloromethane;
DOI:10.1039/c1dt00004g
