trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

Base Information

Chemical Name:trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)
CAS No.:1289037-84-8
Molecular Formula:C₄₄H₂₆N₈O₂Sn
Molecular Weight:817.453
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

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Technology Process of trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

There total 6 articles about trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1289037-82-6
C₄₄H₂₄Cl₂N₈Sn

: 1289037-84-8
trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

Guidance literature:: With potassium carbonate; In methanol; dichloromethane; for 4h; Reflux;
DOI:10.1039/c1dt00004g

Reference yield: 83.0%

: 1289037-82-6
(C₆H₄CN)2(C₅H₄N)2SnC₂₀N₄H₈Cl₂

: 1289037-84-8
trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

Guidance literature:: With K₂CO₃; In methanol; dichloromethane; to soln. of tin complex in CH2Cl2-MeOH (4:1), K2CO3 was added, refluxed for 4 h; washed with water, dried over MgSO4, evapd. in vac., filtered through alumina column (CHCl3-MeOH, 99:1);
DOI:10.1039/c1dt00004g

Reference yield:

: C₄₄H₃₂N₈

: 1289037-84-8
trans-dihydroxy[5,15-bis(4-pyridyl)-10,20-bis(4-cyanophenyl)porphyrinato]tin(IV)

Guidance literature:: Multi-step reaction with 3 steps

1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / tetrahydrofuran / 48 h / 20 °C

2: tin(II) chloride dihdyrate / pyridine / Reflux

3: potassium carbonate / methanol; dichloromethane / 4 h / Reflux

With tin(II) chloride dihdyrate; potassium carbonate; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; pyridine; methanol; dichloromethane;
DOI:10.1039/c1dt00004g