[(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))]

Base Information

• Chemical Name: [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))]
• CAS No.: 1143573-81-2
• Molecular Formula: C₂₈H₄₄N₂Ru
• Molecular Weight: 509.741
• Mol file: 1143573-81-2.mol

Synonyms:

Chemical Property of [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))]

There total 1 articles about [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[(η(5)-pentamethylcyclopentadienyl)RuCl]4 + Li[(t-Bu)NC(mesityl)N(t-Bu)] → [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))] (1143573-81-2)

Guidance literature:

In tetrahydrofuran; (Ar); using Schlenk techniques; addn. of soln. of 4 equiv. of Li((t-Bu)NC(Mes)N(t-Bu)) to suspn. of ((C5Me5)RuCl)4 in THF; stirring at 60°C for 4 h; concn. in vac.; extn. with pentane twice; concn. of extracts in vac.; crystn. at -30°C overnight; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.030

Reference yield: 94.0%

[(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))] (1143573-81-2) + ethenetetracarbonitrile (670-54-2) → [(pentamethylcyclopentadienyl)Ru(κ2-(t-Bu)NC(mesityl)N(t-Bu))(κ1-(N)-tetracyanoethylene)]

Guidance literature:

In tetrahydrofuran; (Ar); using Schlenk techniques; placing of Ru(C5Me5)(((t-Bu)NC(Mes)N(t-Bu)) and TCNE in THF in Schlenk tube; stirring for 4 h at room temp.; filtration, removal of volatiles in vac., dissolving in toluene; concn.;cooling at -30°C; crystn., elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.030