O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Base Information

Chemical Name:O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate
CAS No.:232264-41-4
Molecular Formula:C₄₂H₄₇Cl₃N₂O₁₆
Molecular Weight:942.198
Hs Code.:

O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Synonyms:

Suppliers and Price of O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

There total 4 articles about O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 86520-63-0
2,3,4,6-tetra-O-acetyl-α-galactopyranosyl trichloroacetimidate

: 232264-41-4
O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / TMSOTf / CH₂Cl₂ / 0.75 h / Ambient temperature

2: 83 percent / glacial AcOH, TBAF / tetrahydrofuran / 1 h / ice bath

3: DBU / CH₂Cl₂ / 8 h / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0008-6215(99)00051-8

Reference yield:

: 216877-47-3
tert-butyldimethylsilyl 3,6-di-O-benzyl-2-deoxy-2-dimethylmaleoylamido-glucopyranoside

: 232264-41-4
O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Guidance literature:: Multi-step reaction with 3 steps

1: 84 percent / TMSOTf / CH₂Cl₂ / 0.75 h / Ambient temperature

2: 83 percent / glacial AcOH, TBAF / tetrahydrofuran / 1 h / ice bath

3: DBU / CH₂Cl₂ / 8 h / Ambient temperature

With trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0008-6215(99)00051-8

Reference yield:

: 232264-39-0
tert-butyldimethylsilyl (2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranoside

: 232264-41-4
O-<(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1->4)-3,6-di-O-benzyl-2-deoxy-2-dimethylmaleimido-β-D-glucopyranosyl> trichloroacetimidate

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / glacial AcOH, TBAF / tetrahydrofuran / 1 h / ice bath

2: DBU / CH₂Cl₂ / 8 h / Ambient temperature

With tetrabutyl ammonium fluoride; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; dichloromethane;
DOI:10.1016/S0008-6215(99)00051-8