trans-Re(CO)4(PBz₃)I

Base Information

Chemical Name:trans-Re(CO)4(PBz₃)I
CAS No.:142457-87-2
Molecular Formula:C₂₅H₂₁IO₄PRe
Molecular Weight:729.525
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-Re(CO)4(PBz₃)I

Chemical Property:

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Technology Process of trans-Re(CO)4(PBz₃)I

There total 8 articles about trans-Re(CO)4(PBz₃)I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: Re₂(CO)8(P(CH₂C₆H₅)3)2

: 142457-87-2,142560-44-9
cis-Re(CO)4(PBz₃)I

: 142457-90-7,142560-50-7
cis-Re(CO)4PBz₃Br

: 142457-90-7,142560-50-7
trans-Re(CO)4PBz₃Br

: 142457-87-2,142560-44-9
trans-Re(CO)4(PBz₃)I

Guidance literature:: With iodine; In methanol; dichloromethane; under N2; addn. of soln. of I2 in CH2Cl2 to soln. of complex and NEt4Br (10-fold excess) in CH2Cl2/MeOH; monitored by IR; evapd. (vac.), dissolved in CH2Cl2, filtered, pumped to dryness (vac.), dissolved in C6D6; 1H-, 31P-NMR;

Reference yield: 57.0%

: Re₂(CO)8(P(CH₂C₆H₅)3)2

: 142457-87-2,142560-44-9
cis-Re(CO)4(PBz₃)I

: 142457-90-7,142560-50-7
cis-Re(CO)4PBz₃Br

: 142457-90-7,142560-50-7
trans-Re(CO)4PBz₃Br

: 142457-87-2,142560-44-9
trans-Re(CO)4(PBz₃)I

Guidance literature:: With iodine; In methanol; dichloromethane; under N2; addn. of soln. of I2 in CH2Cl2 to soln. of complex and NEt4Br (10-fold excess) in CH2Cl2/MeOH; monitored by IR; evapd. (vac.), dissolved in CH2Cl2, filtered, pumped to dryness (vac.), dissolved in C6D6; 1H-, 31P-NMR;

Reference yield: 30.0%

: Re₂(CO)8(P(CH₂C₆H₅)3)2

: 142457-87-2,142560-44-9
cis-Re(CO)4(PBz₃)I

: 142457-87-2,142560-44-9
trans-Re(CO)4(PBz₃)I

Guidance literature:: With iodine; In dichloromethane; under N2; slow addn. of soln. of I2 to soln. of complex; addn. of aq. Na2S2O3 soln. after 30 min, organic layer separated, dried (MgSO4), filtered (Celite), evapd. (vac.), trans-product isolated by fractional crystn. (mesitylene), cis-product by column chromy. (silica gel, benzene/hexane); elem. anal.;