η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese

Base Information

• Chemical Name: η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese
• CAS No.: 213816-52-5
• Molecular Formula: C₁₈H₁₃MnN₂O₄
• Molecular Weight: 376.25
• Mol file: 213816-52-5.mol

Synonyms:

Chemical Property of η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese

There total 1 articles about η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

benzylpentacarbonylmanganese + N-(1-phenylethylidene)phenylhydrazine (583-11-9,59130-82-4) → η(2)-(N,C)-2-(1-(N-phenylhydrazono)ethyl)phenyltetracarbonylmanganese (213816-52-5)

Guidance literature:

In n-heptane; byproducts: Mn2(CO)10, CO, PhMe; N2-atmosphere; refluxing hydrazone with slight excess of Mn-complex for 2 h; solvent removal (vac.), chromy. (Al2O3, petroleum ether, then petroleum ether/CH2Cl2); elem. anal.;

DOI:10.1016/S0022-328X(98)00453-7

upstream raw materials:

N-(1-phenylethylidene)phenylhydrazine