trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2]

Base Information

• Chemical Name: trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2]
• CAS No.: 927882-18-6
• Molecular Formula: C₅₈H₆₄Cl₂N₂O₆P₆Pd
• Molecular Weight: 1248.32
• Mol file: 927882-18-6.mol

Synonyms:

Chemical Property of trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2]

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2]

There total 1 articles about trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(C6H5)2PCH2P(C6H5)2NP(OC2H5)2O + dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) → trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2] (927882-18-6)

Guidance literature:

In dichloromethane; byproducts: 1,5-cyclooctadiene; under N2; soln. of Pd complex (0.5 mmol) and PPN-ligand (1.1 mmol) in CH2Cl2 stirred at room temp. for 6 h; concd., Et2O slowly added, ppt. sepd. and washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1039/b609359k

Reference yield: 83.0%

silver hexafluoroantimonate (26042-64-8) + trans-[PdCl2(κ1(P)-Ph2PCH2P(NP(O)(OEt)2)Ph2)2] (927882-18-6) → [Pd(Ph2PCH2P(NP(O)(OEt)2)Ph2)2](SbF6)2

Guidance literature:

In dichloromethane; byproducts: AgCl; under N2; soln. of Pd complex in CH2Cl2 treated with AgSbF6 at room temp. in the absence of light for 2 h; AgCl filtered off, filtrate evapd. to dryness, solid washed with Et2O, dried under vac.; elem. anal.;

DOI:10.1039/b609359k

upstream raw materials:

dichloro(1,5-cyclooctadiene)palladium(II)