(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum

Base Information

• Chemical Name: (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum
• CAS No.: 90623-56-6
• Molecular Formula: C₃₀H₄F₂₀MoO₄P₂
• Molecular Weight: 966.215
• Mol file: 90623-56-6.mol

Synonyms:

Chemical Property of (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum

There total 2 articles about (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,2-bis(di(pentafluorophenyl)phosphino)ethane (76858-94-1) + molybdenum hexacarbonyl (13939-06-5,199620-15-0) → (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum (90623-56-6)

Guidance literature:

In toluene; byproducts: Mo, CO; (N2); soln. of Mo compd. and ligand was refluxed for 12 h, from filtered soln. solvent was removed in vac.; residue was slurried in petroleum ether, filtered and dried in vac.; elem. anal.;

Reference yield: 32.0%

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) (12146-37-1,124717-04-0) + 1,2-bis(di(pentafluorophenyl)phosphino)ethane (76858-94-1) → (1,2-bis(bis(pentafluorophenyl)phosphino)ethane)tetracarbonylmolybdenum (90623-56-6)

Guidance literature:

In acetone; Mo-complex and ligand (molar ratio 1:1.05) in acetone were refluxed under N2 for 72 h; cooled, solvent removed in vac., Mo(CO)4NBD removed at 90°C (0.1mm), residue recrystd. from acetone; elem. anal.;

upstream raw materials:

(bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum⁽⁰⁾

1,2-bis(di(pentafluorophenyl)phosphino)ethane

molybdenum hexacarbonyl

Refernces

• 1、 Ernst, Michael F.,Roddick, Dean M.. "Synthesis and coordination properties of bis(bis(pentafluoroethyl)phosphino)ethane". . p. 1624 - 1627. Retrieved 2008/10/08.