2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene

Base Information

• Chemical Name: 2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene
• CAS No.: 130666-59-0
• Molecular Formula: C₂₈H₁₀Co₄F₄N₃O₁₂P₃
• Molecular Weight: 985.288
• Mol file: 130666-59-0.mol

Synonyms:

Chemical Property of 2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene

There total 1 articles about 2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

2,2-bis(phenylethynyl)tetrafluorocyclotriphosphazene (34671-23-3) + dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 2,4-bis(phenylethynyl)tetrafluorocyclotriphosphazene (93109-60-5) → 2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene (130666-59-0) + cis-2,4-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene + trans-2,4-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene

Guidance literature:

In hexane; (N2); stirring cobalt complex with alkynes in hexane at room temp. for 30 min; evapn., chromy. (SiO2, hexane/CH2Cl2 90:10 vol.), crystn. (hexane, -20°C);

DOI:10.1139/v02-138

Reference yield:

2,2-bis(dicobalt hexacarbonylphenylethynyl)tetrafluorocyclotriphosphazene (130666-59-0) → (Co2(CO)6C6H5CC)2PN(PF2N)2(1-)

Guidance literature:

With cobaltocene; In tetrahydrofuran; dichloromethane; (N2); react. cobalt complexes in a mixt. THF/CH2Cl2 2;1 vol. at -65°C for 5 min; detected by ESR;

DOI:10.1139/v02-138

upstream raw materials:

2,2-bis(phenylethynyl)tetrafluorocyclotriphosphazene

dicobalt octacarbonyl

2,4-bis(phenylethynyl)tetrafluorocyclotriphosphazene