C₄⁽¹³⁾C₆H₁₃NO₄

Base Information

• Chemical Name: C₄⁽¹³⁾C₆H₁₃NO₄
• CAS No.: 1629155-61-8
• Molecular Formula: C₁₀H₁₃NO₄
• Molecular Weight: 217.152
• Mol file: 1629155-61-8.mol

Synonyms:

Chemical Property of C₄⁽¹³⁾C₆H₁₃NO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄⁽¹³⁾C₆H₁₃NO₄

There total 5 articles about C₄⁽¹³⁾C₆H₁₃NO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C4(13)C6H11NO4 (1629155-60-7) → C4(13)C6H13NO4 (1629155-61-8)

Guidance literature:

With sodium tetrahydroborate; ethanol; In ethyl acetate; at 22 ℃; for 1h;

DOI:10.1002/jlcr.3193

Reference yield:

anisole-1,2,3,4,5,6-13C6 (152571-52-3,154492-88-3) → C4(13)C6H13NO4 (1629155-61-8)

Guidance literature:

Multi-step reaction with 5 steps

1: N-Bromosuccinimide / chloroform; N,N-dimethyl-formamide / 70 °C

2: copper(l) iodide; ethyl acetate / N,N-dimethyl-formamide; methanol / 48 h / 80 °C / Sealed tube; Inert atmosphere

3: titanium tetrachloride / dichloromethane / 17 h / -5 - 4 °C / Inert atmosphere

4: ammonium acetate / 2 h / 70 °C

5: sodium tetrahydroborate; ethanol / ethyl acetate / 1 h / 22 °C

With sodium tetrahydroborate; N-Bromosuccinimide; copper(l) iodide; ethanol; ammonium acetate; titanium tetrachloride; ethyl acetate; In methanol; dichloromethane; chloroform; ethyl acetate; N,N-dimethyl-formamide; 3: |Rieche Formylation / 4: |Henry Nitro Aldol Condensation;

DOI:10.1002/jlcr.3193

Reference yield:

1-bromo-4-methoxybenzene-1,2,3,4,5,6-13C6 (1538556-42-1) → C4(13)C6H13NO4 (1629155-61-8)

Guidance literature:

Multi-step reaction with 4 steps

1: copper(l) iodide; ethyl acetate / N,N-dimethyl-formamide; methanol / 48 h / 80 °C / Sealed tube; Inert atmosphere

2: titanium tetrachloride / dichloromethane / 17 h / -5 - 4 °C / Inert atmosphere

3: ammonium acetate / 2 h / 70 °C

4: sodium tetrahydroborate; ethanol / ethyl acetate / 1 h / 22 °C

With sodium tetrahydroborate; copper(l) iodide; ethanol; ammonium acetate; titanium tetrachloride; ethyl acetate; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 2: |Rieche Formylation / 3: |Henry Nitro Aldol Condensation;

DOI:10.1002/jlcr.3193

upstream raw materials:

anisole-1,2,3,4,5,6-¹³C₆

1-bromo-4-methoxybenzene-1,2,3,4,5,6-¹³C₆

1,4-dimethoxy-[¹³C₆]-benzene

2,4-dimethoxy-[¹³C₆]-benzaldehyde