Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside

Base Information

• Chemical Name: Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside
• CAS No.: 24333-05-9
• Molecular Formula: C₁₄H₁₈O₅
• Molecular Weight: 266.294
• DSSTox Substance ID: DTXSID401177937

Synonyms:DTXSID401177937;Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside;24333-05-9

Chemical Property of Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside

Chemical Property:

• XLogP3: 0.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 266.11542367
• Heavy Atom Count: 19
• Complexity: 292

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1C(CC2C(O1)COC(O2)C3=CC=CC=C3)O
• Isomeric SMILES: CO[C@H]1[C@@H](C[C@@H]2[C@H](O1)COC(O2)C3=CC=CC=C3)O

Technology Process of Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside

There total 6 articles about Methyl 3-deoxy-4,6-O-(phenylmethylene)-beta-D-xylo-hexopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(1aR,2S,6R,7aR,7bR)-2-Methoxy-6-phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene (2880-96-8,3150-15-0,3150-16-1,3257-59-8,14187-71-4,15384-57-3,19465-13-5,32976-15-1,52885-37-7,53270-02-3,53270-03-4,65391-11-9,65391-12-0,66537-92-6,67226-04-4,71184-14-0,86420-78-2,86420-79-3,91177-51-4,91177-52-5,117708-93-7,120408-72-2) → (2R,6S,7R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol (14187-72-5,20196-81-0,24332-87-4,24333-05-9,24921-02-6,34266-73-4,40773-64-6,65530-28-1,72904-78-0,72904-79-1,73285-00-4,108740-00-7,138663-47-5) + (2R,6S,8S,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol (6752-48-3,16718-95-9,18424-62-9,19877-02-2,22886-97-1,52153-29-4,52612-68-7,55331-65-2,64978-95-6,65725-24-8,66512-93-4,67968-51-8,72904-80-4,77481-69-7,131615-73-1,138663-49-7,151214-39-0)

Guidance literature:

With bis(cyclopentadienyl)titanium (III) chloride; cyclohexa-1,4-diene;

DOI:10.1021/ja00173a045

Reference yield:

methyl 2,3-anhydro-4,6-dioxabenzylidene-α-D-talopyranose (2880-96-8,3150-15-0,3150-16-1,3257-59-8,14187-71-4,15384-57-3,19465-13-5,32976-15-1,52885-37-7,53270-02-3,53270-03-4,65391-11-9,65391-12-0,66537-92-6,67226-04-4,71184-14-0,86420-78-2,86420-79-3,91177-51-4,91177-52-5,117708-93-7,120408-72-2) → methyl-[O4,O6-((S)-benzylidene)-α-D-lyxo-3-deoxy-hexopyranoside] (14187-72-5,20196-81-0,24332-87-4,24333-05-9,24921-02-6,34266-73-4,40773-64-6,65530-28-1,72904-78-0,72904-79-1,73285-00-4,108740-00-7,138663-47-5)

Guidance literature:

With methanol; nickel; at 100 ℃; under 73550.8 Torr; Hydrogenation;

DOI:10.1002/hlca.19480310627

Reference yield:

methyl-[O4,O6-((S)-benzylidene)-S-methyl-3-thio-β-D-idopyranoside] (16697-40-8,54898-15-6,99146-73-3,144607-23-8,144607-26-1,144607-32-9) → methyl-[O4,O6-((S)-benzylidene)-β-D-lyxo-3-deoxy-hexopyranoside] (14187-72-5,20196-81-0,24332-87-4,24333-05-9,24921-02-6,34266-73-4,40773-64-6,65530-28-1,72904-78-0,72904-79-1,73285-00-4,108740-00-7,138663-47-5)

Guidance literature:

With ethanol; nickel;

DOI:10.1002/hlca.19470300306

upstream raw materials:

benzaldehyde

methyl-(α-D-lyxo-3-deoxy-hexopyranoside)

methyl 2,3-anhydro-4,6-dioxabenzylidene-α-D-talopyranose

methyl-[O⁴,O⁶-((S)-benzylidene)-S-methyl-3-thio-β-D-idopyranoside]

Downstream raw materials:

2,4,6-tri-O-benzyl-3-deoxy-D-xylo-hexopyranoside

methyl 2,4,6-tri-O-benzyl-3-deoxy-β-D-xylo-hexopyranoside

methyl-[O⁴,O⁶-((S)-benzylidene)-O²-methyl-β-D-lyxo-3-deoxy-hexopyranoside]

methyl-[O⁴,O⁶-((S)-benzylidene)-O²-methyl-α-D-lyxo-3-deoxy-hexopyranoside]

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 24333-05-9 (2R,6S,7R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol

Send

Send

Metric Ton KG G Pound L ML

Send

Send