Fe(CO)4(P(C₆H₅)2COCH₃)

Base Information

• Chemical Name: Fe(CO)4(P(C₆H₅)2COCH₃)
• CAS No.: 235751-69-6
• Molecular Formula: C₁₈H₁₃FeO₅P
• Molecular Weight: 396.119
• Mol file: 235751-69-6.mol

Synonyms:

Chemical Property of Fe(CO)4(P(C₆H₅)2COCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(CO)4(P(C₆H₅)2COCH₃)

There total 1 articles about Fe(CO)4(P(C₆H₅)2COCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

iron pentacarbonyl (13463-40-6,37220-42-1) + methyllithium (917-54-4) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → Fe(CO)4(P(C6H5)2COCH3) (235751-69-6)

Guidance literature:

In tetrahydrofuran; diethyl ether; Ar-atmosphere; addn. of equimolar amt. of MeLi (in Et2O) to Fe-complex soln. (in THF, -78°C), warming to 20°C during 2.5 h, addn. of PPh2Cl at -78°C, stirring for 12 h (-78°C to 20°C); evapn., extn. into pentane, crystn.; elem. anal.;

DOI:10.1016/S0022-328X(98)01223-6

Reference yield: 62.0%

sodium tetrahydroborate (16940-66-2) + Fe(CO)4(P(C6H5)2COCH3) (235751-69-6) → Fe(CO)4(PH(C6H5)2) (18399-66-1,38967-68-9)

Guidance literature:

In methanol; Ar-atmosphere; stirring Fe-complex with 3 equiv. of NaBH4 (0°C, 20 min, then 20°C, 30 min); evapn., treatment with H2O and Et2O, drying of org. layer (MgSO4), filtration, evapn.;

DOI:10.1016/S0022-328X(98)01223-6

Reference yield: 42.0%

Fe(CO)4(P(C6H5)2COCH3) (235751-69-6) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → Fe(CO)4(P(C6H5)2C(OP(C6H5)2))CH2 (235751-75-4)

Guidance literature:

With LiN(i)Pr₂; In tetrahydrofuran; byproducts: LiCl; Ar-atmosphere; addn. of slight excess of LiN(i)Pr2 to Fe-complex soln. at -78°C, stirring (-78 to -50°C, 45 min), addn. of slight excess of PPh2Cl at -78°C, stirring (-78°C to 20°C,overnight); filtration, evapn., extn. into pentane, standing at -15°C, evapn.;

DOI:10.1016/S0022-328X(98)01223-6

upstream raw materials:

iron pentacarbonyl

methyllithium

chloro-diphenylphosphine

Downstream raw materials:

Fe(CO)4(PH(C₆H₅)2)

Fe(CO)4(P(C₆H₅)2C(OP(C₆H₅)2))CH₂