(η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt

Base Information

Chemical Name:(η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt
CAS No.:479347-05-2
Molecular Formula:C₃₄H₂₄CoN₃O
Molecular Weight:549.577
Hs Code.:

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Chemical Property of (η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt

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Technology Process of (η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt

There total 1 articles about (η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: sodium azide

: 182627-85-6
(η⁵-carboxycyclopentadienyl)(η⁴-tetraphenylcyclobutadiene)cobalt

: 479347-05-2
(η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt

Guidance literature:: With oxalyl dichloride; tetrabutylammomium bromide; N,N-dimethyl-formamide; In dichloromethane; under N2, Schlenk technique; to soln. of Fe complex (COCl)2 was added followed by a drop of DMF, mixt. was stirred for 3 h, solvent was removed,residue was dissolved in CH2Cl2, Bu4NBr was added, then NaN3, mixt. was stirred for 18 h; water was added, org. layer was sepd., aq. layer was extd. with CH2Cl2, org. layers were dried (MgSO4), filtered, solvent was removed, residue was chromd. (CH2Cl2/petroleum ether); elem. anal.;
DOI:10.1021/om0204989

Reference yield:

: 2916-68-9
2-(Trimethylsilyl)ethanol

: 479347-05-2
(η5-acylazidecyclopentadienyl)(η4-tetraphenylcyclobutadiene)cobalt

: (η5-cyclopentadienyl-1-(2-trimethylsilyl)ethyl carbamate)(η4-tetraphenylcyclobutadiene)cobalt

Guidance literature:: In toluene; under N2, Schlenk technique; soln. of Fe complex was heated to 105°C, and ligand was added, mixt. was stirred at this temp. for 3 h; mixt. was cooled to room temp., NaOH added, soln. stirred for 5 min, org. layer sepd., aq. layer extd. with CH2Cl2, org. layers dried (MgSO4), filtered, solvent removed, residue chromd. (CH2Cl2/petroleum ether), recrystd. from same mixt.; elem. anal.;
DOI:10.1021/om0204989