C₄₄H₆₆O₃Si₂

Base Information

Chemical Name:C₄₄H₆₆O₃Si₂
CAS No.:160423-45-0
Molecular Formula:C₄₄H₆₆O₃Si₂
Molecular Weight:699.177
Hs Code.:

C<sub>44</sub>H<sub>66</sub>O<sub>3</sub>Si<sub>2</sub>

Synonyms:

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Chemical Property of C₄₄H₆₆O₃Si₂

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Technology Process of C₄₄H₆₆O₃Si₂

There total 11 articles about C₄₄H₆₆O₃Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 69739-34-0
t-butyldimethylsiyl triflate

: 160423-44-9
(4E,8E)-(2S,3R,6S,7S)-2,6,8-Trimethyl-1-trityloxy-deca-4,8-diene-3,7-diol

: 160423-45-0
C₄₄H₆₆O₃Si₂

Guidance literature:: With triethylamine; In dichloromethane; at -78 ℃;
DOI:10.1021/jo00104a001

Reference yield:

: 1026731-13-4
(E)-(2R,3R)-5-tert-Butylsulfanyl-3-hydroxy-2-methyl-pent-4-enal

: 160423-45-0
C₄₄H₆₆O₃Si₂

Guidance literature:: Multi-step reaction with 10 steps

1: DIBAL / tetrahydrofuran / -78 °C

2: DMAP, Et₃N / CH₂Cl₂

4: 92 percent / LDA, TBSCl / 1.) THF, -78 deg C, 2.) HMPA, -78 to 65 deg C

5: N,N-carbonyldiimidazole

6: t-BuLi / diethyl ether / -78 - -40 °C

7: 80 percent / NaBH₄, CeCl₃ / dimethylsulfoxide

8: m-CPBA / CH₂Cl₂ / -78 °C

9: P(OMe)3 / methanol

10: Et₃N / CH₂Cl₂ / -78 °C

With dmap; sodium tetrahydroborate; cerium(III) chloride; tert.-butyl lithium; diisobutylaluminium hydride; tert-butyldimethylsilyl chloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; 1,1'-carbonyldiimidazole; lithium diisopropyl amide; phosphorous acid trimethyl ester; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00104a001

Reference yield:

: 160423-37-0
(E)-(2S,3R)-5-tert-Butylsulfanyl-2-methyl-pent-4-ene-1,3-diol

: 160423-45-0
C₄₄H₆₆O₃Si₂

Guidance literature:: Multi-step reaction with 9 steps

1: DMAP, Et₃N / CH₂Cl₂

3: 92 percent / LDA, TBSCl / 1.) THF, -78 deg C, 2.) HMPA, -78 to 65 deg C

4: N,N-carbonyldiimidazole

5: t-BuLi / diethyl ether / -78 - -40 °C

6: 80 percent / NaBH₄, CeCl₃ / dimethylsulfoxide

7: m-CPBA / CH₂Cl₂ / -78 °C

8: P(OMe)3 / methanol

9: Et₃N / CH₂Cl₂ / -78 °C

With dmap; sodium tetrahydroborate; cerium(III) chloride; tert.-butyl lithium; tert-butyldimethylsilyl chloride; triethylamine; 3-chloro-benzenecarboperoxoic acid; 1,1'-carbonyldiimidazole; lithium diisopropyl amide; phosphorous acid trimethyl ester; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1021/jo00104a001