C₃₈H₃₁ClF₃IrO₄P₂S

Base Information

• Chemical Name: C₃₈H₃₁ClF₃IrO₄P₂S
• CAS No.: 105881-07-0
• Molecular Formula: C₃₈H₃₁ClF₃IrO₄P₂S
• Molecular Weight: 930.343
• Mol file: 105881-07-0.mol

Synonyms:

Chemical Property of C₃₈H₃₁ClF₃IrO₄P₂S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₃₈H₃₁ClF₃IrO₄P₂S

There total 2 articles about C₃₈H₃₁ClF₃IrO₄P₂S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + trifluorormethanesulfonic acid (1493-13-6) → carbonylchlorohydrido(trifluoromethanesulphonato)bis(triphenylphosphine)iridium(III) (78350-77-3,105881-07-0,82535-01-1)

Guidance literature:

In dichloromethane; mixing Ir-complex suspn. with CF3SO3H (Ar); pptn. from soln. with n-pentane, 3x washing with n-pentane; vac. drying;

Reference yield: 70.0%

bis(triphenylphosphine)iridium(I) carbonyl chloride (15318-31-7,14871-41-1,59246-46-7) + trifluorormethanesulfonic acid (1493-13-6) + N-methyltrimethylacetonitrilium trifluoromethanesulfonate → carbonylchlorohydrido(trifluoromethanesulphonato)bis(triphenylphosphine)iridium(III) (78350-77-3,105881-07-0,82535-01-1)

Guidance literature:

In chloroform; Ar; the mixture was protected from light and stirred for 30 min;; diethyl ether was added until turbidity persisted and the solution was kept at -10 ° C overnight;;

DOI:10.1016/0022-328X(93)80217-Y

Reference yield: 92.0%

C38H31ClF3IrO4P2S (105881-07-0,78350-77-3,82535-01-1) + triphenylphosphine (603-35-0) → Carbonylchlorohydridotris(triphenylphosphan)iridium(III)-trifluormethansulfonat (82474-51-9,82510-07-4)

Guidance literature:

In dichloromethane; by addn. of P(C6H5)3 into soln. of Ir complex under dry Ar at -78°C; warmed to room temp. then pptd. by addn. of n-pentane; calcd. amts.of educts; centrifuged, decanted, washed with n-pentane, dried in high vac.; elem.anal.;

upstream raw materials:

bis(triphenylphosphine)iridium(I) carbonyl chloride

trifluorormethanesulfonic acid

Downstream raw materials:

Carbonylchlorohydrido(thiocyanato-S)bis(triphenylphosphan)iridium(III)

Carbonylchlorohydridotris(triphenylphosphan)iridium(III)-trifluormethansulfonat