(C₁₁H₈)2Pt(P(C₆H₅)3)2

Base Information

• Chemical Name: (C₁₁H₈)2Pt(P(C₆H₅)3)2
• CAS No.: 97719-84-1
• Molecular Formula: C₅₈H₄₆P₂Pt
• Molecular Weight: 1000.03
• Mol file: 97719-84-1.mol

Synonyms:

Chemical Property of (C₁₁H₈)2Pt(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

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Technology Process of (C₁₁H₈)2Pt(P(C₆H₅)3)2

There total 1 articles about (C₁₁H₈)2Pt(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tris(triphenylphosphine)platinum(0) (13517-35-6) + 8-bromo-5H-benzocycloheptene (97719-86-3) → (C11H8)2Pt(P(C6H5)3)2 (97719-84-1)

Guidance literature:

With potassium tert-butoxide; In tetrahydrofuran; Pt complex and an excess of t-BuOK dissolving in THF in a dry box, connecting to a N2 line, cycloheptatriene soln. adding dropwise over 10 min at 0°C, stirring and allowing to come to room temp. overnight, filtering through Celite, evapg.; identified by elem. anal., IR and NMR spectra;

DOI:10.1021/om00129a037

Reference yield:

(C11H8)2Pt(P(C6H5)3)2 (97719-84-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → (C11H8)2Pt((C6H5)2PCH2CH2P(C6H5)2)

Guidance literature:

In benzene; Pt complex refluxing with a ligand in benzene; identified by (13)C NMR spectrum;

DOI:10.1021/om00129a037

upstream raw materials:

tris(triphenylphosphine)platinum⁽⁰⁾

8-bromo-5H-benzocycloheptene