((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2)

Base Information

• Chemical Name: ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2)
• CAS No.: 847591-43-9
• Molecular Formula: C₄₀H₄₇F₃O₂Ru₂Si₂
• Molecular Weight: 875.118
• Mol file: 847591-43-9.mol

Synonyms:

Chemical Property of ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2)

There total 3 articles about ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

((η5-C5Me5)Ru(μ-η2-HSiPh2))2(μ-H)(H) (141365-60-8) + trifluoroacetic acid (76-05-1) → ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2) (847591-43-9)

Guidance literature:

In toluene; byproducts: H2, C6H6; (Ar); addn. of CF3COOH to mixt. of Ru complex and toluene at -20°C, stirring at -20°C for 2 h, warming to room temp., stirring at 23°C for 2 h; evapn. under vac., residue washed with pentane, dried under vac.; elem. anal.;

DOI:10.1021/om049328h

Reference yield:

((η5-C5Me5)Ru)2(μ-η2-HSiPh2)(μ-SiPh2)(μ-CF3CO2)(μ-H)(H) (847591-47-3) + water (7732-18-5) → ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OH))(μ-SiPh2) (847591-51-9) + ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2) (847591-43-9)

Guidance literature:

With sodium acetate; In tetrahydrofuran; water; acetone; (Ar); soln. of sodium acetate in water/acetone (1/2) added in drops to mixt. of Ru complex and THF at -78°C, slowly warmed to room temp.,stirred at room temp. for 3 h; evapn. under vac., residue extd. with toluene, extract filtered through celite, filtrate evapd.; mixt. not sepd., detected by NMR spectroscopy;

DOI:10.1021/om049328h

Reference yield:

((η5-C5Me5)Ru)2(μ-η2-HSiPh2)(μ-SiPh2)(μ-CF3CO2)(μ-H)(H) (847591-47-3) → ((η5-C5Me5)Ru(μ-H))2(μ-SiPh(OCOCF3))(μ-SiPh2) (847591-43-9)

Guidance literature:

In toluene; byproducts: benzene; (Ar); soln. of Ru complex in toluene warmed from -20°C to room temp.;

DOI:10.1021/om049328h

upstream raw materials:

((η5-C5Me5)Ru)2(μ-η2-HSiPh2)(μ-SiPh2)(μ-CF3CO2)(μ-H)(H)

water

((η5-C5Me5)Ru(μ-η2-HSiPh2))2(μ-H)(H)

trifluoroacetic acid

Downstream raw materials:

((η5-C5Me5)Ru)2(μ-η2-HSiPh2)(μ-η2-HSiPh(OCOCF3))(μ-H)(H)

((η5-C5Me5)Ru(μ-H))2(μ-Si(OMe)Ph)(μ-SiPh2)