[3,5-(t)Bu₂C₆D₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆D₃]Pt(Me)(p-Tol)

Base Information

• Chemical Name: [3,5-(t)Bu₂C₆D₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆D₃]Pt(Me)(p-Tol)
• CAS No.: 878663-72-0
• Molecular Formula: C₄₀H₅₈N₂Pt
• Molecular Weight: 767.946
• Mol file: 878663-72-0.mol

Synonyms:

Chemical Property of [3,5-(t)Bu₂C₆D₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆D₃]Pt(Me)(p-Tol)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [3,5-(t)Bu₂C₆D₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆D₃]Pt(Me)(p-Tol)

There total 1 articles about [3,5-(t)Bu₂C₆D₃N=C(Me)C(Me)=N-3,5-(t)Bu₂C₆D₃]Pt(Me)(p-Tol) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

PtCl(methyl)(dimethyl sulfide)2 + (C6(2)H3(C(CH3)3)2NCCH3)2 + p-tolyllithium (2417-95-0) → [3,5-(t)Bu2C6D3N=C(Me)C(Me)=N-3,5-(t)Bu2C6D3]Pt(Me)(p-Tol) (878663-72-0)

Guidance literature:

In hexane; under N2; soln. of p-tolyllithium in Me2S/hexane added to soln. of Pt complex in Me2S at -78°C, stirring overnight, addn. of tert-butyl bromide to remove excess of Li reagent, soln. of diimine in CH2Cl2 added,warming to room temp.; evapn. under vac, residue dissolved in CH2Cl2, filtration through Celite, filtrate stirred at room temp. for 4 h, filtration through alumina, filtrate evapd., residue washed with pentane, dried under vac.;

DOI:10.1021/om050899z

upstream raw materials:

p-tolyllithium