Pd₂Cl₂(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

Base Information

• Chemical Name: Pd₂Cl₂(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄
• CAS No.: 925222-58-8
• Molecular Formula: C₄₀H₄₁Cl₂N₂P₂Pd₂S*ClO₄
• Molecular Weight: 1026.99

Synonyms:

Chemical Property of Pd₂Cl₂(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

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Useful:

Technology Process of Pd₂Cl₂(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

There total 1 articles about Pd₂Cl₂(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

dichloro bis(acetonitrile) palladium(II) (21264-30-2,90243-59-7,14592-56-4) + lithium perchlorate trihydrate + (4-tert-butyl-2,6-bis((2-(diphenylphosphino)ethylimino)methyl)phenyl)(tert-butyl)sulfane (925222-55-5) → Pd2Cl2(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol(1-))ClO4 (925222-58-8)

Guidance literature:

In methanol; N,N-dimethyl-formamide; acetonitrile; (under Ar, Schlenk); Pd-complex in MeCN added to soln. of ligand in MeCN, stirred for 2 d, evapd. to dryness, redissolved in DMF, soln. of LiClO4*3H2O in MeOH added; ppt. filtered, air dried, recrystd. from MeCN; elem. anal.;

DOI:10.1039/b613789j

Reference yield: 75.0%

sodium azide + lead(II) perchlorate + Pd2Cl2(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol(1-))ClO4 (925222-58-8) → Pd2(N3)2(2,6-bis((2-(diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol(1-))ClO4 (925222-66-8)

Guidance literature:

In methanol; water; acetonitrile; byproducts: PbCl2; (under Ar, Schlenk); soln. of Pb(ClO4)2 in MeCN added to Pd-complex in MeCN, stirred for 4 h, filtered, soln. of NaN3 in aq. MeOH added; concd. in vacuo, diluted with EtOH, concd., ppt. filtered, washed with EtOH, dried in air;

DOI:10.1039/b613789j

Reference yield: 63.0%

lead(II) perchlorate + Pd2Cl2(2,6-bis((2-diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol(1-))ClO4 (925222-58-8) + tetra-(n-butyl)ammonium iodide (311-28-4) → Pd2I2(2,6-bis((2-(diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol(1-))ClO4 (925222-68-0)

Guidance literature:

In methanol; water; acetonitrile; byproducts: PbCl2; (under Ar, Schlenk); soln. of Pb(ClO4)2 in MeCN added to Pd-complex in MeCN, stirred for 4 h, filtered, soln. of N(CH3(CH2)3)4I in aq. MeOH added; concd. in vacuo, diluted with EtOH, concd., ppt. filtered, washed with EtOH, dried in air; elem. anal.;

DOI:10.1039/b613789j

upstream raw materials:

dichloro bis(acetonitrile) palladium(II)

(4-tert-butyl-2,6-bis((2-(diphenylphosphino)ethylimino)methyl)phenyl)(tert-butyl)sulfane

Downstream raw materials:

Pd₂(N₃)2(2,6-bis((2-(diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

Pd₂I₂(2,6-bis((2-(diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

Pd₂(CN)2(2,6-bis((2-(diphenylphosphino)ethylimino)methyl)-4-tert-butylbenzenethiol^(1-))ClO₄

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