hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron

Base Information

• Chemical Name: hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron
• CAS No.: 99833-12-2
• Molecular Formula: C₁₇H₂₀Fe₂O₆S
• Molecular Weight: 464.102
• Mol file: 99833-12-2.mol

Synonyms:

Chemical Property of hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron

There total 1 articles about hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

sodium tetrahydroborate (16940-66-2) + hexacarbonyl(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron (84433-24-9,61793-17-7) → hexacarbonyl(2,2,6,6-tetramethylcyclohexanethiocarbaldehyde)diiron (99833-12-2)

Guidance literature:

With hydrochloric acid; In methanol; water; under N2: addn. of NaBH4 to a soln. of thioketene-compound in methanol with stirring; addn. of H2O after 30 min; twice washing with hexane; dropwise addn. of concd. HCl to the methanolic phase with stirring til acidic reaction;; soln. was extd. with hexane, hexane phase shaken with a satd. NaHCO3 soln., dried over MgSO4, concd. under vac., chromy. (Kieselgel, hexane), eluate was evapd. in vacuo at room temp., residue dried under high vac. for 20 min; oil;

DOI:10.1016/0022-328X(85)80073-5

upstream raw materials:

sodium tetrahydroborate

hexacarbonyl(μ-1,1,3,3-teramethyl-2-thiocarbonylcyclohexane)diiron