tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

Base Information

Chemical Name:tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron
CAS No.:106828-17-5
Molecular Formula:C₂₅H₂₈FeO₃Si₂
Molecular Weight:488.514
Hs Code.:

Synonyms:

Suppliers and Price of tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

There total 3 articles about tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 106873-02-3
1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene

: 106828-17-5
tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

: 106828-16-4
tricarbonyl(1,1-dimethyl-3,6-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

Guidance literature:: In toluene; a mixt. of the diene, Fe(CO)5 and dry toluene is heated in an autoclave at 160°C for 22 h; solvent and excess Fe(CO)5 are removed in vac. and the residue is sepd. by TLC on silica gel;
DOI:10.1246/bcsj.59.1509

Reference yield: 20.5%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 106873-00-1
1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,5-diene

: 106828-17-5
tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

: 106828-16-4
tricarbonyl(1,1-dimethyl-3,6-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

: 106828-15-3
tricarbonyl(1,1-dimethyl-2,5-diphenyl-6-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

: 106873-01-2
1,1-dimethyl-2,5-diphenyl-6-trimethylsilyl-1-silacyclohexa-2,5-diene

Guidance literature:: In toluene; a mixt. of the diene, Fe(CO)5 and dry toluene is heated in a small autoclave at 165°C for 20 h; solvent and excess Fe(CO)5 are removed in vac. and the residue is sepd. by TLC on silica gel; elem. anal.;
DOI:10.1246/bcsj.59.1509

Reference yield:

: 106828-16-4
tricarbonyl(1,1-dimethyl-3,6-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

: 106828-17-5
tricarbonyl(1,1-dimethyl-2,5-diphenyl-4-trimethylsilyl-1-silacyclohexa-2,4-diene)iron

Guidance literature:: In solid; thermolysis by sealing under vac. in a Pyrex tube and heating in an oil bath at 170°C for 7 h; sepn. of 2,5-diphenyl-compd. from unreacted 3,6-diphenyl-compd. by TLC;
DOI:10.1246/bcsj.59.1509