dibromo{tris(diethyl dithiocarbamato)}niobium

Base Information

• Chemical Name: dibromo{tris(diethyl dithiocarbamato)}niobium
• CAS No.: 128930-50-7
• Molecular Formula: C₁₅H₃₀Br₂N₃NbS₆
• Molecular Weight: 697.534
• Mol file: 128930-50-7.mol

Synonyms:

Chemical Property of dibromo{tris(diethyl dithiocarbamato)}niobium

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of dibromo{tris(diethyl dithiocarbamato)}niobium

There total 2 articles about dibromo{tris(diethyl dithiocarbamato)}niobium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

μ-dinitrogen-bis{tris(diethyl dithiocarbamato)niobium} → dibromo{tris(diethyl dithiocarbamato)}niobium (128930-50-7,129263-37-2) + hydrazine (302-01-2,78206-91-4,119775-10-9,75013-58-0)

Guidance literature:

With deuterium bromide; In acetonitrile; React. under N2 at 25.0°C.; Monitored spectrophotometrically at 400-420 nm.; Kinetics;

DOI:10.1039/DT9900001101

Reference yield:

{(methylphenylhydrazido)tris(diethyl dithiocarbamato)niobium} → dibromo{tris(diethyl dithiocarbamato)}niobium (128930-50-7,129263-37-2) + C6H5(CH3)NHNH3(2+)*2BF4(1-)={C6H5(CH3)NHNH3}{BF4}2

Guidance literature:

With tetrafluoroboric acid diethyl ether; In dichloromethane; Under N2, addn. of anhyd. HBr (in MeOH+SiMe3Br) to a soln. of Nb-complex in CH2Cl2, stirring (15 min), addn. of HBF4*OEt2.; (1)H-NMR, IR.;

DOI:10.1039/DT9900001093