{Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

Base Information

Chemical Name:{Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2
CAS No.:114378-79-9
Molecular Formula:6C₃H₇NO*2C₇H₇O₃S*Ru
Molecular Weight:882.032
Hs Code.:

Synonyms:

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Chemical Property of {Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

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Technology Process of {Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

There total 1 articles about {Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 15694-44-7
hexaaquaruthenium(II) tosylate

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 122-51-0
orthoformic acid triethyl ester

: 114378-79-9
{Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

Guidance literature:: In N,N-dimethyl-formamide; Ru complex is added to DMF which has been satd. with Ar. To the stirred soln. O2-free triethyl orthoformate is added and left for 18 h in the dark at room temp.; redn. of volume by vacuum distn., cooling in an ice bath, addn. of diethyl ether with vigorous stirring, filtn. of product, washing with ether, drying in vacuo for 2 h in the dark;
DOI:10.1021/ja00184a030

Reference yield: 82.0%

: 114378-79-9
{Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

: 10428-50-9
tri-(2-pyridyl)amine

: 114466-50-1
bis{tris(2-pyridyl)amine}ruthenium(II) tosylate

Guidance literature:: In propan-1-ol; {Ru(DMF)6}(tos)2 was added to a degassed (Ar) soln. of tris(2-pyridyl)amine in dry propan-1-ol. The soln. was refluxed overnight, during which time it changed from a light orange color to an intense yellow-orange.; The solvent was removed under reduced pressure, and the residue was recrystd. from ethanol/ether. Elem.anal.;

Reference yield: 67.0%

: 114378-79-9
{Ru(N,N-dimethylformamide)6}(4-toluenesulfonate)2

: 26437-48-9
tris(2-pyridyl)phosphine

: 114378-78-8
bis{tris(2-pyridyl)phosphine}ruthenium(II) tosylate ethanolate

Guidance literature:: In propan-1-ol; {Ru(DMF)6}(tos)2 was added to a degassed (Ar) soln. of tris(2-pyridyl)phosphine in dry propan-1-ol. The soln. was refluxed overnight.; The solvent was removed. Elem.anal.;