(C₆H₅CH(OCH₃)C₆H₅)Cr(CO)3

Base Information

• Chemical Name: (C₆H₅CH(OCH₃)C₆H₅)Cr(CO)3
• CAS No.: 67235-67-0
• Molecular Formula: C₁₇H₁₄CrO₄
• Molecular Weight: 334.292
• Mol file: 67235-67-0.mol

Synonyms:

Chemical Property of (C₆H₅CH(OCH₃)C₆H₅)Cr(CO)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₆H₅CH(OCH₃)C₆H₅)Cr(CO)3

There total 2 articles about (C₆H₅CH(OCH₃)C₆H₅)Cr(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

benzhydroltricarbonylchromium(0) (12155-17-8) → (C6H5CH(OCH3)C6H5)Cr(CO)3 (67235-67-0)

Guidance literature:

With methanol; sulfuric acid; In methanol; To a soln. of complex in CH3OH was added concd. H2SO4 at -14°C with stirring (N2 atm.);,; the mixt. was added to an ice-water, extd. with ether, the org. layer was dried over MgSO4, filtered, evapd., chromd. on silica gel plates (ether-hexane); elem. anal.;;

DOI:10.1016/S0022-328X(00)93566-6

Reference yield: 54.0%

(benzophenone)tricarbonylchromium(0) (12147-92-1) → (C6H5CH(OCH3)C6H5)Cr(CO)3 (67235-67-0)

Guidance literature:

With methylene chloride; In N,N-dimethyl-formamide; Electrolysis; Under Ar, with Bu4NPF6 or Bu4NBF4 at -1.40 V with a Hg-pool electrode.; Dilution of catolyte with H2O, extg. (Et2O), drying, evapn. of solvent, column chromy. (Et2O/hexane).;

DOI:10.1016/0022-328X(87)80070-0

upstream raw materials:

benzhydroltricarbonylchromium⁽⁰⁾

(benzophenone)tricarbonylchromium(0)