Technology Process of bis[bis(4-methylphenyl)bismuthino]selenide
There total 7 articles about bis[bis(4-methylphenyl)bismuthino]selenide which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
dichloromethane;
addn. of black Se powder to Bi compd. soln., 0°C; vigorously stirring with exclusion of light, finally at room temp., 2h; filtration at 0°C; reducing volume; addn. of pentane; placing on solid CO2, overnight; decantation, washing (several times with ice-cold pentane); drying (vac.); elem. anal.;
- Guidance literature:
-
With
piperidine;
In
diethyl ether;
byproducts: 1-(4-methoxybenzoyl)piperidine; to a suspn. of Bi-compound in diethyl ether was added a soln. of piperidine in diethyl ether at room temp., the mixt. was stirred at 0°C for 2 h; evapd., recrystd. from ethyl acetate/hexane 2/1;
DOI:10.1002/hlca.200690070
- Guidance literature:
-
With
piperidine;
In
dichloromethane;
byproducts: 1-(4-methylbenzoyl)piperidine; to a suspn. of Bi-compound in CH2Cl2 was added a soln. of piperidine in CH2Cl2 at room temp., the mixt. was stirred at 0°C for 2 h; evapd., recrystd. from ethyl acetate/hexane 2/1;
DOI:10.1002/hlca.200690070
