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bis[bis(4-methylphenyl)bismuthino]selenide

Base Information
  • Chemical Name:bis[bis(4-methylphenyl)bismuthino]selenide
  • CAS No.:114245-29-3
  • Molecular Formula:C28H28Bi2Se
  • Molecular Weight:861.451
  • Hs Code.:
bis[bis(4-methylphenyl)bismuthino]selenide

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Chemical Property of bis[bis(4-methylphenyl)bismuthino]selenide
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Technology Process of bis[bis(4-methylphenyl)bismuthino]selenide

There total 7 articles about bis[bis(4-methylphenyl)bismuthino]selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In dichloromethane; addn. of black Se powder to Bi compd. soln., 0°C; vigorously stirring with exclusion of light, finally at room temp., 2h; filtration at 0°C; reducing volume; addn. of pentane; placing on solid CO2, overnight; decantation, washing (several times with ice-cold pentane); drying (vac.); elem. anal.;
Guidance literature:
With piperidine; In diethyl ether; byproducts: 1-(4-methoxybenzoyl)piperidine; to a suspn. of Bi-compound in diethyl ether was added a soln. of piperidine in diethyl ether at room temp., the mixt. was stirred at 0°C for 2 h; evapd., recrystd. from ethyl acetate/hexane 2/1;
DOI:10.1002/hlca.200690070
Guidance literature:
With piperidine; In dichloromethane; byproducts: 1-(4-methylbenzoyl)piperidine; to a suspn. of Bi-compound in CH2Cl2 was added a soln. of piperidine in CH2Cl2 at room temp., the mixt. was stirred at 0°C for 2 h; evapd., recrystd. from ethyl acetate/hexane 2/1;
DOI:10.1002/hlca.200690070
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