bis(1,2-bis(diphenylphosphino)ethane)-chlororhodi

Base Information

• Chemical Name: bis(1,2-bis(diphenylphosphino)ethane)-chlororhodi
• CAS No.: 14874-99-8
• Molecular Formula: C₅₂H₄₈P₄Rh*Cl
• Molecular Weight: 935.207
• Mol file: 14874-99-8.mol

Synonyms:

Chemical Property of bis(1,2-bis(diphenylphosphino)ethane)-chlororhodi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(1,2-bis(diphenylphosphino)ethane)-chlororhodi

There total 13 articles about bis(1,2-bis(diphenylphosphino)ethane)-chlororhodi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[{Rh(DPPE)(μ2-Cl)}2] (53204-14-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → bis(1,2-bis(diphenylphosphino)ethane)rhdium(I) chloride (15043-47-7,14874-99-8)

Guidance literature:

In tetrahydrofuran; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2019.02.009

Reference yield: 92.0%

Wilkinson's catalyst (14694-95-2) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → bis(1,2-bis(diphenylphosphino)ethane)rhdium(I) chloride (15043-47-7,14874-99-8)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

DOI:10.1039/c5cc09156j

Reference yield: 73.0%

hydrido{1,2-bis-(diphenylphosphino)ethane}rhodium (29189-87-5) + chloroform (67-66-3,8013-54-5) → [Rh(bis(diphenyl)phosphinoethane)2][Cl] (15043-47-7,14874-99-8)

Guidance literature:

hydrido{1,2-bis-(diphenylphosphino)ethane}rhodium; With pentaphenylcyclopentaphosphane; In tetrahydrofuran; for 1h; Reflux;

chloroform; In hexane;

DOI:10.1021/acs.orglett.7b03825

upstream raw materials:

RhCl((Z)-2-methyl-1,3-dianilinopent-1-ene)

1,2-bis-(diphenylphosphino)ethane

rhodium(III)chloride

[(norbornadiene)rhodium(I)chloride]2

Downstream raw materials:

{Rh-bis(1,2-bis(diphenylphosphino)ethane))}ClO₄

[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]⁽¹⁺⁾*Cl^(1-)=[Rh(S₂)((C₆H₅)2PC₂H₄P(C₆H₅)2)2]Cl

[Rh(C₂H₄(P(C₆H₅)2)2)2]⁽¹⁺⁾*SnClBr₂^(1-)=[Rh(C₂H₄(P(C₆H₅)2)2)2]SnClBr₂

bis(1,2-bis(diphenylphosphino)ethane)rhodium(I) triflate

Refernces

• 1、 Arisawa, Mieko,Sawahata, Kyosuke,Yamada, Tomoki,Sarkar, Debayan,Yamaguchi, Masahiko. "Rhodium-Catalyzed Insertion Reaction of PhP Group of Pentaphenylcyclopentaphosphine with Acyclic and Cyclic Disulfides". . p. 938 - 941. Retrieved 2018/02/23.
• 2、 Clegg, William,Lawlor, Fiona J.,Marder, Todd B.,Nguyen, Paul,Norman, Nicholas C.,Orpen, A. Guy,Quayle, Michael J.,Rice, Craig R.,Robins, Edward G.,Scott, Andrew J.,Souza, Fabio E. S.,Stringer, Graham,Whittell, George R.. "Boron-boron bond oxidative addition to rhodium(I) and iridium(I) centres". . p. 301 - 309. Retrieved 2007/10/03.